Recent progress in synthetic applications of hypervalent iodine (III) reagents

A Yoshimura, VV Zhdankin - Chemical Reviews, 2024 - ACS Publications
Hypervalent iodine (III) compounds have found wide application in modern organic
chemistry as environmentally friendly reagents and catalysts. Hypervalent iodine reagents …

The chemistry of heterocycles in the 21st century

VN Charushin, EV Verbitskiy, ON Chupakhin… - Uspekhi Khimii, 2024 - mathnet.ru
The chemistry of heterocyclic compounds has traditionally been and remains a bright area of
chemical science in Russia. This is due to the fact that many heterocycles find the widest …

Halogen Bond Unlocks Ultra‐High Birefringence

J Chen, MB Xu, HY Wu, JY Wu, KZ Du - Angewandte Chemie, 2024 - Wiley Online Library
Anisotropy is crucial for birefringence (Δn) in optical materials, but optimizing it remains a
formidable challenge (Δn> 0.3). Supramolecular frameworks incorporating π‐conjugated …

A Halogen‐Bonded Organic Framework (XOF) Emissive Cocrystal for Acid Vapor and Explosive Sensing, and Iodine Capture

S Maji, R Natarajan - Small, 2023 - Wiley Online Library
There is a strong and urgent need for efficient materials that can capture radioactive iodine
atoms from nuclear waste. This work presents a novel strategy to develop porous materials …

Key-to-lock halogen bond-based tetragonal pyramidal association of iodonium cations with the lacune rims of beta-octamolybdate

NS Soldatova, AD Radzhabov, DM Ivanov… - Chemical …, 2024 - pubs.rsc.org
The structure-directing “key-to-lock” interaction of double σ-(IIII)-hole donating iodonium
cations with the O-flanked pseudo-lacune rims of [β-Mo8O26] 4− gives halogen-bonded …

Halogen‐Bonded Organic Frameworks (XOFs) Based on N⋅⋅⋅Br+⋅⋅⋅N Bonds: Robust Organic Networks Constructed by Fragile Bonds

X Bai, Z Tian, H Dong, N Xia, J Zhao… - Angewandte Chemie …, 2024 - Wiley Online Library
Organic frameworks face a trade‐off between the framework stability and the bond
dynamics, which necessitates the development of innovative linkages that can generate …

Noncovalent Chelation by Halogen Bonding in the Design of Metal-Containing Arrays: Assembly of Double σ-Hole Donating Halolium with CuI-Containing O,O …

AV Semenov, SV Baykov, NS Soldatova… - Inorganic …, 2023 - ACS Publications
Five new copper (I) complexes─ composed of the paired dibenzohalolium and [CuL2]−(L=
1, 2, 4-oxadiazolate) counterions in which O, O-atoms of the anion are simultaneously linked …

Hypervalent Iodine (III)‐Based Complexation for Chiroptical Supramolecular Glass, Deep Eutectic Solvent and Luminescent Switch

S An, A Hao, P Xing - Advanced Materials, 2024 - Wiley Online Library
Hypervalent iodine (III) have widely been utilized for organic synthetic reagents. They are
also recognized as positive charge‐assisted, exceptionally robust biaxial halogen bond …

Push–Pull and Conventional Nitriles as Halogen Bond Acceptors in Their Cocrystals with Iodo-Substituted Perfluorobenzenes

YN Toikka, RM Gomila, A Frontera… - Crystal Growth & …, 2023 - ACS Publications
Co-crystallization of the push–pull nitriles NCNR2 (R2= Me2 1, C4H8 2, C5H10 3, and
C4H8O 4) with iodo-substituted perfluorobenzenes (1, 4-diiodotetrafluorobenzene− 1, 4-FIB …

Triphenylphosphine Oxide: A Versatile Covalent Functionality for Carbon Nanotubes

Y Pan, D Baster, D Käch, J Reger… - Angewandte Chemie …, 2024 - Wiley Online Library
Broadening the scope of functionalities that can be covalently bound to single‐walled
carbon nanotubes (SWCNTs) is crucial for enhancing the versatility of this promising …