New stories of zeolite structures: their descriptions, determinations, predictions, and evaluations

Y Li, J Yu - Chemical reviews, 2014 - ACS Publications
Zeolites are an important class of inorganic crystalline materials that have been widely used
in the fields of petroleum refining, petrochemical industry, and fine chemical industry, as …

Illuminating the Black Box: A Perspective on Zeolite Crystallization in Inorganic Media

K Asselman, C Kirschhock… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Since the discovery of synthetic zeolites in the 1940s and their implementation
in major industrial processes involving adsorption, catalytic conversion, and ion exchange …

In situ imaging of silicalite-1 surface growth reveals the mechanism of crystallization

AI Lupulescu, JD Rimer - Science, 2014 - science.org
The growth mechanism of silicalite-1 (MFI zeolite) is juxtaposed between classical models
that postulate silica molecules as primary growth units and nonclassical pathways based on …

Fast nucleation and growth of ZIF-8 nanocrystals monitored by time-resolved in situ small-angle and wide-angle X-ray scattering.

J Cravillon, CA Schröder, R Nayuk… - … (International ed. in …, 2011 - europepmc.org
Prenucleation clusters: in situ synchrotron X-ray scattering with a one-second time resolution
revealed the occurrence of nano-sized clusters during the nucleation and early growth of …

Toward high-throughput zeolite membranes

M Tsapatsis - Science, 2011 - science.org
Many energy-conservation strategies in manufacturing rely on replacing or combining
thermally driven separation processes such as distillation with more efficient ones …

UV Raman spectroscopic study on the synthesis mechanism and assembly of molecular sieves

F Fan, Z Feng, C Li - Chemical Society Reviews, 2010 - pubs.rsc.org
In the past decade, UV Raman spectroscopy has become a powerful technique for the
characterization of the synthesis mechanism and assembly of molecular sieves. Ultraviolet …

Nucleation of Porous Crystals from Ion-Paired Prenucleation Clusters

N Pellens, N Doppelhammer… - Chemistry of …, 2022 - ACS Publications
Current nucleation models propose manifold options for the formation of crystalline
materials. Exploring and distinguishing between different crystallization pathways on the …

Methods for in situ spectroscopic probing of the synthesis of a zeolite

A Aerts, CEA Kirschhock, JA Martens - Chemical Society Reviews, 2010 - pubs.rsc.org
Unraveling the crystallization mechanism of zeolites remains an increasingly important
challenge in chemistry. During the last decade, in situ spectroscopic methods have provided …

Crystal engineering of metal–organic framework thin films for gas separations

DJ Babu, G He, LF Villalobos… - … Sustainable Chemistry & …, 2018 - ACS Publications
Metal–organic frameworks or MOFs have witnessed a phenomenal rise owing to a highly
tunable synthetic chemistry allowing flexibility in the selection of its constituents, namely …

Multinuclear MAS NMR Monitoring of the Effect of Silicate Speciation on the Mechanism of Zeolite BEA Formation: Toward Engineering of Crystal Size and …

II Ivanova, EP Andriako, IA Kostyukov… - Crystal Growth & …, 2023 - ACS Publications
Time-resolved in situ 13C, 27Al, and 29Si MAS NMR and ex situ XRD, X-ray fluorescence,
and TG studies have been applied for the elucidation of the mechanisms of hydrothermal …