This Review examines recent developments in late transition metal-catalyzed
hydroamination and-amidation reactions. A hydroamination is a reaction in which an N− H …

This review highlights key reactivities relying on C–C bond cleavages of cyclopropenes.
Metal-catalyzed and metal-free transformations are covered in reactions involving direct ring …

Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …

Three-membered carbocycles are extremely important versatile building blocks for organic
chemistry. Their unique structural and electronic properties give rise to an array of very …

Abstract Herein, a copper (I)‐catalyzed asymmetric hydrophosphination of 3, 3‐disubstituted
cyclopropenes is reported. It provides a series of phosphine derivatives in high to excellent …

The search for efficient and selective routes for the synthesis of chiral aminocyclopropane
derivatives is of great interest and importance as these structures are important components …

Aryl sulfides were obtained from the coupling reaction of S-aryl (or S-alkyl) thioacetates and
aryl bromides in the presence of palladium catalyst. This reaction method enables the one …

In this article, we advance Rh-catalyzed hydrothiolation through the divergent reactivity of
cyclopropenes. Cyclopropenes undergo hydrothiolation to provide cyclopropyl sulfides or …

2, 3, 4-or 2, 3, 5-trisubstituted furans were highly regioselectively formed from the
cycloisomerization reaction of the same starting cyclopropenes 1 via the subtle choice of the …

Dirhodium tetrakis ((S)-N-(dodecylbenzenesulfonyl) prolinate)(Rh2 (S-DOSP) 4) is an
effective catalyst for highly enantioselective cyclopropenation reactions between terminal …