Diverse emission properties of transition metal complexes beyond exclusive single phosphorescence and their wide applications

K Li, Y Chen, J Wang, C Yang - Coordination Chemistry Reviews, 2021 - Elsevier
Luminescence properties and excited state reactivities of photoactive transition metal
complexes have been harnessed for various applications in the fields of electroluminescent …

Tuning the luminescence of transition metal complexes with acyclic diaminocarbene ligands

MA Kinzhalov, EV Grachova… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Metal complexes featuring acyclic diaminocarbene ligands have recently emerged as
powerful emitters for prospective use in OLEDs and other electroluminescent technologies …

Cyanide‐Assembled d10 Coordination Polymers and Cycles: Excited State Metallophilic Modulation of Solid‐State Luminescence

A Belyaev, T Eskelinen, TM Dau… - … A European Journal, 2018 - Wiley Online Library
The series of cyanide‐bridged coordination polymers [(P2) CuCN] n (1),[(P2) Cu {M (CN) 2}]
n (M= Cu 3, Ag 4, Au 5) and molecular tetrametallic clusters [{(P4) MM'(CN)} 2] 2+(MM …

Emission and Luminescent Vapochromism Control of Octahedral Cu4I4 Complexes by Conformationally Restricted P,N Ligands

I Strelnik, A Shamsieva… - … A European Journal, 2023 - Wiley Online Library
Abstract A conformationally restricted P, N‐ligand capable of the design of polynuclear
copper (I) complexes was synthesized via the reaction of primary pyridylphosphine …

Excitation-Wavelength-Dependent and Auxiliary-Ligand-Tuned Intersystem-Crossing Efficiency in Cyclometalated Platinum (II) Complexes: Spectroscopic and …

K Li, GSM Tong, J Yuan, C Ma, L Du, C Yang… - Inorganic …, 2020 - ACS Publications
Understanding the factors affecting the intersystem-crossing (ISC) rate constant (k ISC) of
transition-metal complexes is crucial to material design with tailored photophysical …

Binuclear Gold (I) Phosphine Alkynyl Complexes Templated on a Flexible Cyclic Phosphine Ligand: Synthesis and Some Features of Solid-State Luminescence

ID Strelnik, VV Sizov, VV Gurzhiy, AS Melnikov… - Inorganic …, 2019 - ACS Publications
A flexible bidentate cyclic phosphine, namely, 1, 5-bis (p-tolyl)-3, 7-bis (pyridin-2-yl)-1, 5-
diaza-3, 7-diphosphacyclooctane (PNNP), was used as a template to construct a family of …

Excitation-dependent multiple fluorescence of a substituted 2-(2′-hydroxyphenyl) benzoxazole

QJ Meisner, AH Younes, Z Yuan… - The Journal of …, 2018 - ACS Publications
Excitation-dependent multiple fluorescence of a 2-(2′-hydroxyphenyl) benzoxazole (HBO)
derivative (1) is described. Compound 1 contains the structure of a charge-transfer (CT) 4 …

A Smart Phosphine–Diyne Polymer Displays “Turn-On” Emission with a High Selectivity for Gold (I/III) Ions

HK Mackenzie, BW Rawe, K Samedov… - Journal of the …, 2020 - ACS Publications
A polymeric phosphine sensor is reported that exhibits bright blue fluorescence in the
presence of gold (I/III) ions but is nonemissive with other metal ions. Specifically, solutions of …

Ligand design and nuclearity variation towards dual emissive Pt (II) complexes for singlet oxygen generation, dual channel bioimaging, and theranostics

MZ Shafikov, AF Suleymanova, RJ Kutta… - Journal of Materials …, 2022 - pubs.rsc.org
Organic ligands comprising thiophene ring (s) afford complexes of transition metals, such as
Pt (II) and Ir (III), with photoluminescence readily tunable via ligand modifications. In this …

Just add the gold: Aggregation-induced-emission properties of alkynylphosphinegold (I) complexes functionalized with phenylene–terpyridine subunits

EO Abramova, AV Paderina, SO Slavova… - Inorganic …, 2021 - ACS Publications
A series of organometallic complexes containing an alkynylphosphinegold (I) fragment and
a phenylene–terpyridine moiety connected together by flexible linker have been prepared …