Oxidative addition and reductive elimination are key steps in a wide variety of catalytic
reactions mediated by transition-metal complexes. Historically, this reactivity has been …

The chemistry of group 14 element (II) hydride complexes has rapidly expanded since the
first stable example of such a compound was reported in 2000. Since that time it has …

Since the latter quarter of the twentieth century, main group chemistry has undergone
significant advances. Power's timely review in 2010 highlighted the inherent differences …

Since the first heavy alkene analogues of germanium and tin were isolated in 1976, followed
by West's disilene in 1981, the chemistry of stable group 14 dimetallenes and dimetallynes …

Since the first report of their isolation in 2007, magnesium (i) dimers have transitioned from
being chemical curiosities to versatile reducing agents that are used by an ever-increasing …

The conversion of CO2 into multicarbon (C2+) compounds by reductive homocoupling offers
the possibility to transform renewable energy into chemical energy carriers and thereby …

Solid-state auride salts featuring the negatively charged Au–ion are known to be stable in
the presence of alkali metal counterions. While such electron-rich species might be …

The past decade has witnessed staggering progress in the chemistry of compounds with low‐
valent main‐group elements. Although these discoveries are mostly fundamental by nature …

Abstract Gallaphosphene L (Cl) GaPGaL (2; L= HC [C (Me) N (2, 6‐i‐Pr2C6H3)] 2), which is
synthesized by reaction of LGa (Cl) PCO (1) with LGa, reacts with [Na (OCP)(dioxane) 2.5] to …

Intramolecular germylene, stannylene, and plumbylene Lewis pairs were reacted with
hexanal and yielded the cyclic addition products only with the germanium and tin reagents …