Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

Organoboronates represent a cornerstone functional group in modern synthesis owing to
their unique reactivity and divergent synthetic capability. Copper catalysis has become one …

Conspectus The oxindole scaffold is a privileged structural motif that is found in a variety of
bioactive targets and natural products. Moreover, derivatives of the oxindole structure are …

Catalytic asymmetric C–C bond formation with alkylcopper intermediates as carbon
nucleophiles is now textbook chemistry. Related chemistry with boron and silicon …

Quinazolinones are common substructures in molecules of medicinal importance. We report
an enantioselective copper‐catalyzed borylative cyclization for the assembly of privileged …

An unprecedented redox-neutral annulation reaction of tertiary anilines with electron-
deficient alkynes was developed that proceeds through a cascade Friedel–Crafts …

The catalytic asymmetric borylation of conjugated carbonyls followed by stereoselective
intramolecular cascade cyclizations with in situ generated chiral enolates are extremely rare …

Borylation has become a powerful method to synthesize organoboranes as versatile
building blocks in organic synthesis, medicinal chemistry, and materials science. Copper …

A distinct class of C 1-symmetric N-heterocyclic carbene (NHC) ligands possessing a chiral
fused tetrahydroquinoline ring and a chiral N-arylmethyl group was designed and …