Electrostatic interactions within mixed-valent compounds

A Hildebrandt, D Miesel, H Lang - Coordination Chemistry Reviews, 2018 - Elsevier
The electrochemical properties of bi-and multi-metallic compounds are a convolution of
several factors, among which through-bond electron transfer and through-space electrostatic …

(Multi) ferrocenyl five-membered heterocycles: excellent connecting units for electron transfer studies

A Hildebrandt, H Lang - Organometallics, 2013 - ACS Publications
The electro-and spectroelectrochemical behavior of diverse (multi) ferrocenyl five-
membered heterocyclic compounds, including furan, thiophene, pyrroles, phospholes, etc. is …

Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles

D Miesel, A Hildebrandt, H Lang - Current Opinion in Electrochemistry, 2018 - Elsevier
Molecular electrochemistry of multi-redox functionalized 5-membered heterocycles -
ScienceDirect Skip to main contentSkip to article Elsevier logo Journals & Books Search …

Di-and triferrocenyl (hetero) aromatics: Synthesis, characterization,(spectro-) electrochemistry, and calculations

U Pfaff, A Hildebrandt, D Schaarschmidt, T Hahn… - …, 2012 - ACS Publications
A series of di-and triferrocenyl (hetero) aromatics including 2, 5-diferrocenylpyridine (4), 2, 6-
diferrocenylpyridine (5), 1, 3, 5-triferrocenylbenzene (9), 2, 4, 6-triferrocenylpyridine (10) …

Electron transfer studies on ferrocenylthiophenes: synthesis, properties, and electrochemistry

JM Speck, R Claus, A Hildebrandt, T Rüffer… - …, 2012 - ACS Publications
The ferrocenylthiophenes 2, 3-Fc2-c C4H2S (9), 2, 4-Fc2-c C4H2S (10), and 2, 3, 4-Fc3-c
C4HS (11) have been prepared by a 2-or 3-fold Negishi cross-coupling reaction of the …

Synthesis and (Spectro)electrochemical Behavior of 2,5-Diferrocenyl-1-phenyl-1H-phosphole

D Miesel, A Hildebrandt, M Korb, PJ Low… - Organometallics, 2013 - ACS Publications
2, 5-Diferrocenyl-1-phenyl-1 H-phosphole (3) has successfully been prepared by a
cyclization reaction of phenylphosphine with 1, 4-diferrocenyl butadiyne. Subsequent …

Molecular wires using (oligo) pyrroles as connecting units: An electron transfer study

U Pfaff, A Hildebrandt, D Schaarschmidt… - …, 2013 - ACS Publications
A series of (oligo) pyrroles featuring redox-active terminal ferrocenyl groups (Fc2-(c
C4H2NPh) n (4, n= 1; 9, n= 2; 16, n= 3; 20, n= 4)) has been prepared using a Negishi C, C …

Ferrocenyl-based di-and trinuclear lanthanide complexes: solid state structures,(spectro) electrochemical and DFT studies

A Khalladi, E Kovalski, MA Abdulmalic, T Rüffer… - Dalton …, 2023 - pubs.rsc.org
Dinuclear and trinuclear ferrocenylcarboxylato-bridged lanthanide complexes of type [Ln
(μO: κ2OO′-O2CFc)(O2CFc) 2 (H2O)(dmf)] 2·(dmf) 2 (Ln= Sm (2), Eu (3), Gd (4), Tb (5); Fc …

Synthesis, characterization, electrochemistry, and computational studies of ferrocenyl-substituted siloles

SW Lehrich, A Hildebrandt, T Rüffer, M Korb… - …, 2014 - ACS Publications
Ferrocenylsiloles of the type 2, 5-Fc2-3, 4-Ph2-c C4SiR2 (3a, R= Me; 3b, R= Ph) have been
prepared by reductive cyclization from diethynylsilanes, followed by ferrocenylation using …

Influence of P‐Bonded Bulky Substituents on Electronic Interactions in Ferrocenyl‐Substituted Phospholes

D Miesel, A Hildebrandt, M Korb… - … A European Journal, 2015 - Wiley Online Library
Diferrocenyl‐1‐Ar‐1H‐phospholes 3 a–e (Ar= phenyl (a), ferrocenyl (b), mesityl (c), 2, 4, 6‐
triphenylphenyl (d), and 2, 4, 6‐tri‐tert‐butylphenyl (e)) have been prepared by reactions of …