Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Cooperatively bimetallic organic catalysis, coupling actions of two metal centers in a
catalytic organic transformation via co‐activation of a single molecule or synergistic …

The field of multimetallic catalysis is rapidly developing and some multimetallic complexes
catalyze organic transformations to yield the desired products in more efficient ways owing …

Photoredox/transition-metal dual catalysis has become a hot research topic in the
development of methodologies. Density functional theory (DFT) calculations have been …

A naphthyridine‐derived expanded pincer ligand is described that can host two copper (I)
centers. The proton‐responsive ligand can undergo reversible partial and full …

Intermediate amide complexes of NHC-ligated monovalent nickel in Buchwald–Hartwig
amination of aryl halides were isolated and structurally characterized. The amide complexes …

While Catellani reactions have become increasingly important for arene functionalizations,
they have been solely catalyzed by palladium. Here we report the first nickel-catalyzed …

The development of dinuclear transition metal catalysis has gained considerable momentum
in recent years. The synergistic interaction between two metals enables the development of …

The direct catalytic alkynylation/dehydrative cyclization of 2-amino-3-trifluoroacetyl-pyridines
on water was developed for the efficient synthesis of a broad range of fluorinated 1, 8 …

Conspectus Multimetallic cofactors supported by weak-field donors frequently function as
reaction centers in metalloproteins, and many of these cofactors catalyze small molecule …