The defined linear arrangement of metal atoms in discrete coordination complexes or
polymers is still one of the most intriguing challenges in synthetic chemistry. These chain …

Recent years have witnessed a meteoric rise in the utilization of carbenes as ligands for the
synthesis of coinage metal complexes due to their potential application in various fields. One …

The discovery of cisplatin antitumor properties in 1969 encouraged researchers to design
metal-based anticancer drugs. Recently, research on N-heterocyclic carbene-based metal …

The polymeric linear chain [AuTl (C6Cl5) 2] n reacts with three terpyridine-type ligands
substituted with thiophene groups containing N-donor centres in different relative positions …

Three four-coordinate N-heterocyclic carbene (NHC) copper (I) complexes,[Cu (Py-
Im)(POP)](PF6)(P1),[Cu (Py-BenIm)(POP)](PF6)(P2), and [Cu (Py-c-BenIm)(POP)](PF6)(P3) …

In the trinuclear, heterometallic cluster compound [Au2CuCl2 (P∩ N) 2] PF6 metallophilic
interactions give rise to very efficient cold-white light emission as a result of at least two …

Synthetic routes to the crystallization of two new box-like complexes,[Au6 (Triphos) 4
(CuBr2)](OTf) 5·(CH2Cl2) 3·(CH3OH) 3·(H2O) 4 (1) and [Au6 (Triphos) 4 (CuCl2)](PF6) …

To force metal ions in heterometallic coinage metal complexes into preset compartments, we
have synthesized a ligand with two N-heterocyclic carbenes (NHCs) separated by a …

The assembly of two different building blocks,[{Au (C6F5) 2}{PbCl (terpy)}](terpy= 2, 2′: 6′:
2′′‐terpyridine) and [{Au (C6F5) 2} 2 {Pb (terpy)}] n, acting as terminal or central pieces …

As a dimetal‐binding rigid scaffold, 2‐(pyridin‐2‐yl) imidazo [1, 5‐b] pyridazine‐7‐ylidene
was introduced. The scaffold was first converted into a meridional Au, N, N‐tridentate ligand …