Cu (II)-mediated methylthiolation of aryl C− H bonds with DMSO
An unprecedented Cu (II)-mediated methylthiolation of aryl C− H bonds under oxidative
conditions that employs the widely available DMSO as the methylthiolation reagent is …
conditions that employs the widely available DMSO as the methylthiolation reagent is …
Copper-mediated methylthiolation of aryl halides with DMSO
F Luo, C Pan, L Li, F Chen, J Cheng - Chemical Communications, 2011 - pubs.rsc.org
A copper-mediated methylthiolation of aryl halides with the widely available DMSO is
described. The procedure tolerates a series of functional groups such as methoxy, nitro …
described. The procedure tolerates a series of functional groups such as methoxy, nitro …
Highly mono-selective ortho-methylthiolation of benzamides via cobalt-catalyzed sp 2 C–H activation
A highly mono-selective ortho-methylthiolation of benzamides was achieved via Co-
catalyzed coupling of benzamides with DMSO. The reaction employs an 8-aminoquinoline …
catalyzed coupling of benzamides with DMSO. The reaction employs an 8-aminoquinoline …
Investigation of the scope and mechanism of copper catalyzed regioselective methylthiolation of aryl halides
Methylthiolation of structurally diverse aryl halides was accomplished under fluoride free
conditions using catalytic amounts of CuI, and DMSO as the methylthiolation source …
conditions using catalytic amounts of CuI, and DMSO as the methylthiolation source …
Highly regioselective para-methylthiolation/bridging methylenation of arylamines promoted by NH 4 I
Y Xu, T Cong, P Liu, P Sun - Organic & Biomolecular Chemistry, 2015 - pubs.rsc.org
Aryl methyl thioethers and methylene-bridged arylamines were synthesized via highly
regioselective para-methylthiolation/bridging methylenation of arylamines using DMSO as …
regioselective para-methylthiolation/bridging methylenation of arylamines using DMSO as …
A convenient method for the synthesis of aryl methyl sulfides via Cu (I)-mediated methylthiolation of haloarenes with DMSO
An efficient process for the Cu (I)-mediated methylthiolation of haloarenes using simple and
readily available DMSO as a convenient and environment friendly source of SMe moiety has …
readily available DMSO as a convenient and environment friendly source of SMe moiety has …
Copper-catalyzed decarboxylative methylthiolation of aromatic carboxylate salts with DMSO
A novel copper-catalyzed decarboxylative methylthiolation of arenecarboxylate salts has
been realized using DMSO as the methylthiolation source. Various potassium aryl …
been realized using DMSO as the methylthiolation source. Various potassium aryl …
A direct and mild conversion of tertiary aryl amides to methyl esters using trimethyloxonium tetrafluoroborate: A very useful complement to directed metalation …
GE Keck, MD McLaws, TT Wager - Tetrahedron, 2000 - Elsevier
The scope and generality of a direct process for the conversion of tertiary amides directly to
methyl esters has been investigated. The process involves a two-step, one pot procedure in …
methyl esters has been investigated. The process involves a two-step, one pot procedure in …
Synthesis and structural features of copper (II) complexes of benzoic acid and methyl substituted benzoic acid hydrazides and X-ray structure of Cu [C6H5CONHNH2] …
OA Odunola, IO Adeoye, JAO Woods - Synthesis and reactivity in …, 2002 - Taylor & Francis
The synthesis, spectroscopic, magnetic and biological activities of copper (II) complexes of
benzoic acid hydrazides (BAH) and o, m, and p-substituted methylbenzoic acid hydrazides …
benzoic acid hydrazides (BAH) and o, m, and p-substituted methylbenzoic acid hydrazides …
Directed metallation of aromatic compounds
J Clayden - The chemistry of organolithium compounds, 2004 - Wiley Online Library
Ortholithiation—the directed metallation of an aromatic ring adjacent to a heteroatom
containing functional group—has arguably overtaken classical electrophilic aromatic …
containing functional group—has arguably overtaken classical electrophilic aromatic …