The halogen bond
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …
Halogen bonding in supramolecular chemistry
LC Gilday, SW Robinson, TA Barendt… - Chemical …, 2015 - ACS Publications
Supramolecular chemistry is “the chemistry of the intermolecular bond, covering the
structures and functions of the entities formed by association of two or more chemical …
structures and functions of the entities formed by association of two or more chemical …
Halogen bonding, chalcogen bonding, pnictogen bonding, tetrel bonding: Origins, current status and discussion
L Brammer - Faraday Discussions, 2017 - pubs.rsc.org
The role of the closing lecture in a Faraday Discussion is to summarise the contributions
made to the Discussion over the course of the meeting and in so doing capture the main …
made to the Discussion over the course of the meeting and in so doing capture the main …
Confronting Sulfur Electrode Passivation and Li Metal Electrode Degradation in Lithium‐Sulfur Batteries Using Thiocyanate Anion
Salt anions with a high donor number (DN) enable high sulfur utilization in lithium‐sulfur (Li‐
S) batteries by inducing three‐dimensional (3D) Li2S growth. However, their insufficient …
S) batteries by inducing three‐dimensional (3D) Li2S growth. However, their insufficient …
Unravelling the potential of sigma hole-assisted co-crystallization: Highlighting recent developments
In the past several decades, the field of cocrystal engineering has developed into a vital
research topic in supramolecular chemistry, holding the foremost scope in crystal …
research topic in supramolecular chemistry, holding the foremost scope in crystal …
Diaryliodonium as a double σ-hole donor: The dichotomy of thiocyanate halogen bonding provides divergent solid state arylation by diaryliodonium cations
NS Soldatova, PS Postnikov, VV Suslonov… - Organic Chemistry …, 2020 - pubs.rsc.org
X-ray crystallography data revealed the dichotomy of thiocyanate-involving noncovalent
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …
interactions in [Ar1Ar2I](SCN), as reflected in the generation of two types of supramolecular …
Coordination of anions by noncovalently bonded σ-hole ligands
Research on σ-hole interactions that include halogen, chalcogen, pnicogen, and tetrel
bonding has been accelerating in recent years. These cousins of the H-bond have many …
bonding has been accelerating in recent years. These cousins of the H-bond have many …
Comparison of the DFT-SAPT and canonical EDA schemes for the energy decomposition of various types of noncovalent interactions
OA Stasyuk, R Sedlak, CF Guerra… - Journal of Chemical …, 2018 - ACS Publications
Interaction energies computed with density functional theory can be divided into physically
meaningful components by symmetry-adapted perturbation theory (DFT-SAPT) or the …
meaningful components by symmetry-adapted perturbation theory (DFT-SAPT) or the …
Halogen bonding in the co-crystallization of potentially ditopic diiodotetrafluorobenzene: a powerful tool for constructing multicomponent supramolecular assemblies
Halogen bonding is emerging as a significant driving force for supramolecular self-assembly
and has aroused great interest during the last two decades. Among the various halogen …
and has aroused great interest during the last two decades. Among the various halogen …
Electron belt-to-σ-hole switch of noncovalently bound iodine (I) atoms in dithiocarbamate metal complexes
Co-crystallization of dithiocarbamate complexes [MII (S2CNEt2) 2](M= Cu 1, Ni 2, Pd 3, Pt 4)
and 1, 3, 5-triiodotrifluorobenzene (FIB) gives an isomorphic series of (1–4)· 2FIB co-crystals …
and 1, 3, 5-triiodotrifluorobenzene (FIB) gives an isomorphic series of (1–4)· 2FIB co-crystals …