Modeling intramolecular energy transfer in lanthanide chelates: A critical review and recent advances

ANC Neto, EES Teotonio, GF de Sá, HF Brito… - Handbook on the …, 2019 - Elsevier
A critical review on the mechanisms and behavior of 4f intraconfigurational transitions in
controllable chemical environments related to nonradiative intramolecular energy transfer …

Tunable optical molecular thermometers based on metallacrowns

EV Salerno, AN Carneiro Neto… - Journal of the …, 2022 - ACS Publications
The effect of ligands' energy levels on thermal dependence of lanthanide emission was
examined to create new molecular nanothermometers. A series of Ln2Ga8L8′ L8 …

Unusually Large Ligand Field Splitting in Anionic Europium (III) Complexes Induced by a Small Imidazolic Counterion

L Blois, IF Costa, J Honorato… - Inorganic …, 2024 - ACS Publications
Luminescent trivalent lanthanide (Ln3+) complexes are compounds of technological interest
due to their unique photophysical properties, particularly anionic tetrakis complexes, given …

A Subtle Change in the Flexible Achiral Spacer Does Matter in Supramolecular Chirality: Two‐Fold Odd‐Even Effect in Polymer Assemblies

H Dai, R Hong, Y Ma, X Cheng… - Angewandte Chemie …, 2023 - Wiley Online Library
Precise control over the chirality and morphologies of polymer assemblies, a remaining
challenge for both chemists and materials scientists, is receiving ever‐increasing attention in …

[HTML][HTML] A tutorial review on the nonradiative energy transfer rates between lanthanide ions

ANC Neto, RT Moura, JAA Coelho… - Chinese Journal of …, 2023 - cjl.lightpublishing.cn
In this tutorial review, we present nonradiative energy transfer (ET) rates between
lanthanides in a rearranged form. We emphasize the nature of the contributions which are …

Unusual alternating crystallization-induced emission enhancement behavior in nonconjugated ω-phenylalkyl tropylium salts

RD Crocker, DP Pace, B Zhang… - Journal of the …, 2021 - ACS Publications
The alternating physical properties, especially melting points, of α, ω-disubstituted n-alkanes
and their parent n-alkanes had been known since Baeyer's report in 1877. There is …

Elucidation of LMCT excited states for lanthanoid complexes: a theoretical and solid-state experimental framework

E Rousset, M Piccardo, RW Gable, M Massi… - Inorganic …, 2022 - ACS Publications
Photophysical and magnetic properties arising from both ground and excited states of
lanthanoid ions are relevant for numerous applications. These properties can be …

Overlap integrals and excitation energies calculations in trivalent lanthanides 4f orbitals in pairs Ln-L (L= Ln, N, O, F, P, S, Cl, Se, Br, and I)

ANC Neto, RT Moura Jr - Chemical Physics Letters, 2020 - Elsevier
In this work, DFT-based calculations of overlap integrals (ρ) and excitations energies (Δε)
associated with the diatomic-like pairs Ln 3+-Ligand and Ln-Ln'are presented. The ρ and Δε …

Odd–even effect in chiral side-chain cyanobiphenyl block copolymer assemblies prepared by polymerization-induced chiral self-assembly

J Guo, Z Tang, H Dai, D Liu, Z He, X Cheng, W Zhang - Nanoscale, 2024 - pubs.rsc.org
The precise control of the chirality of polymer assemblies is a challenge faced by scientists
and has received significant attention in recent years. In this study, we employed the …

Novel trivalent europium β-diketonate complexes with N-(pyridine-2-yl) amides and N-(pyrimidine-2-yl) amides as ancillary ligands: Photophysical properties and …

GBV Lima, JC Bueno, AF da Silva, ANC Neto… - Journal of …, 2020 - Elsevier
Eighteen new Eu 3+ complexes and their Gd 3+ analogues with 1, 3-diketonate as main
ligands and N-(pyridine-2-yl) amides or N-(pyrimidine-2-yl) amides as ancillary ligands were …