Probing the free volume in polymers by means of positron annihilation lifetime spectroscopy

G Consolati, D Nichetti, F Quasso - Polymers, 2023 - mdpi.com
Positron annihilation lifetime spectroscopy (PALS) is a valuable technique to investigate
defects in solids, such as vacancy clusters and grain boundaries in metals and alloys, as …

Construction and ion transport-related applications of the hydrogel-based membrane with 3D nanochannels

Y Hou, S Ma, J Hao, C Lin, J Zhao, X Sui - Polymers, 2022 - mdpi.com
Hydrogel is a type of crosslinked three-dimensional polymer network structure gel. It can
swell and hold a large amount of water but does not dissolve. It is an excellent membrane …

Exploration of free volume behavior and ionic conductivity of PVA: x (x= 0, Y2O3, ZrO2, YSZ) ion-oxide conducting polymer ceramic composites

C Chavan, RF Bhajantri, V Cyriac, S Bulla… - Journal of Non …, 2022 - Elsevier
This article presents a comparative analysis of three distinct zirconia-inserted polyvinyl
alcohol (PVA) polymer matrices. X-ray diffraction, Fourier transform infrared spectroscopy …

Effect of Al2O3 on Nanostructure and Ion Transport Properties of PVA/PEG/SSA Polymer Electrolyte Membrane

HFM Mohamed, EE Abdel-Hady, MMY Abdel-Moneim… - Polymers, 2022 - mdpi.com
Polymer electrolyte membrane (PEM) fuel cells have the potential to reduce our energy
consumption, pollutant emissions, and dependence on fossil fuels. To achieve a wide range …

Nanostructure analysis and dielectric properties of PVA/sPTA proton exchange membrane for fuel cell applications: Positron lifetime study

WM Mohammed, S Awad, EE Abdel-Hady… - Radiation Physics and …, 2023 - Elsevier
Proton exchange membranes made of cross-linked polyvinyl alcohol and sulfophthalic acid
(PVA-sPTA) were successfully fabricated by casting method and crosslinked at 100° C with …

Highly flexible SCOF proton exchange membrane reinforced with PTFE to enhance fuel cell power density

H Zhao, B Pang, F Cui, W Chen, G Xie, X Wu… - Journal of Membrane …, 2025 - Elsevier
Sulfonated covalent organic frameworks (SCOFs) facilitate rapid proton conduction through
densely ordered sulfonic acid groups, however, the brittleness of COFs self-supporting …

Positron annihilation lifetime study of subnano level free volume features of grafted polymer electrolyte membranes for hydrogen fuel cell applications

TD Tap, TH Long, DTT Hieu, LH Hao… - Polymers for …, 2022 - Wiley Online Library
The subnano level free‐volume hole features of poly (styrene sulfonic acid)(PSSA) grafted
poly (ethylene‐co‐tetrafluoroethylene) polymer electrolyte membranes (ETFE‐PEMs) are …

Positron annihilation techniques as probes for investigation of the polymer electrolyte membranes with different ion exchange capacities

HFM Mohamed - Journal of the Egyptian Society for Basic Sciences …, 2024 - journals.ekb.eg
The positron annihilation lifetime (PAL) experiments have been conducted on pure
polyether sulfone (PES) and sulfonated polyether sulfone (SPES) with varying degrees of …

[HTML][HTML] Investigation of the Impact of an Electric Field on Polymer Electrolyte Membranes for Fuel Cell Applications

HFM Mohamed, EE Abdel-Hady, MHM Hassanien… - Physics, 2024 - mdpi.com
A systematic study was carried out on Nafion® 112 membranes to evaluate the effects of
different electric field strengths on the structural and electrical properties of the membranes …