In the last decade, major conceptual advances in the chemistry of actinide molecules and
materials have been made to demonstrate their distinct reactivity profiles as compared to …

The exploration of macromolecular topology provides common ground amongst chemists,
material scientists, mathematicians, and artists. Fascinating polymer architectures, ranging …

New aluminium scorpionate based complexes have been prepared and used for the
synthesis of cyclic carbonates from epoxides and carbon dioxide. Bimetallic aluminium …

Structurally diverse macrocycles and medium‐sized rings (9–24 membered scaffolds, 22
examples) can be generated through a telescoped acylation/ring‐expansion sequence …

Parallel catalyst screening was used to develop new aluminium scorpionate based catalysts
for the synthesis of cyclic carbonates from epoxides and carbon dioxide. Nineteen …

A simple and effective synthetic route to cyclic polymers has been developed based on the
following sequence:(i) selective cyclization of two self-complementary sec-ammonium …

Topology transformation of a star polymer to a linear polymer is demonstrated for the first
time. A three‐armed star polymer possessing a mechanical linking of two polymer chains …

In this review article, we discuss the synthesis and dynamic nature of macromolecular
systems that have mechanically linked polymer chains capable of undergoing a topology …

A simple and efficient method to generate macrocyclic structures has been developed based
on the dynamic behavior of the linker bis (2, 2, 6, 6‐tetramethylpiperidin‐1‐yl) disulfide …

We report a convenient and scalable synthesis of cyclic poly (ε-caprolactone)(PCL) from its
linear counterpart based on the rotaxane protocol. Cyclic PCL was prepared by ring …