Disassembling iron availability to phytoplankton

Y Shaked, H Lis - Frontiers in Microbiology, 2012 - frontiersin.org
The bioavailability of iron to microorganisms and its underlying mechanisms have far
reaching repercussions to many natural systems and diverse fields of research, including …

Predicting the bioavailability of metals and metal complexes: critical review of the biotic ligand model

VI Slaveykova, KJ Wilkinson - Environmental Chemistry, 2005 - CSIRO Publishing
Environmental Context. The chemical speciation of trace metals greatly influences their
biological effects. Nonetheless, no clear consensus currently exists as to when metal …

Al (III) and Fe (III) binding by humic substances in freshwaters, and implications for trace metal speciation

E Tipping, C Rey-Castro, SE Bryan… - … et cosmochimica acta, 2002 - Elsevier
Published experimental data for Al (III) and Fe (III) binding by fulvic and humic acids can be
explained approximately by the Humic Ion-Binding Model VI. The model is based on …

Analytical methods for determination of free metal ion concentration, labile species fraction and metal complexation capacity of environmental waters: A review

M Pesavento, G Alberti, R Biesuz - Analytica Chimica Acta, 2009 - Elsevier
Different experimental approaches have been suggested in the last few decades to
determine metal species in complex matrices of unknown composition as environmental …

Sources, sinks, and cycling of dissolved organic copper binding ligands in the ocean

A Ruacho, C Richon, H Whitby… - Communications Earth & …, 2022 - nature.com
Organic Cu-binding ligands have a fundamental influence on Cu distributions in the global
ocean and they complex> 99% of the dissolved Cu in seawater. Cu-binding ligands …

Iron-binding ligands and their role in the ocean biogeochemistry of iron

KA Hunter, PW Boyd - Environmental Chemistry, 2007 - CSIRO Publishing
Environmental context. It is now well accepted that iron is an essential micronutrient for
phytoplankton growth in many areas of the global ocean, even though this element is …

The role of humic-type ligands in the bioavailability and stabilization of dissolved iron in the Western Tropical South Pacific Ocean

G Dulaquais, P Fourrier, C Guieu, L Mahieu… - Frontiers in Marine …, 2023 - frontiersin.org
The high N2 fixation rate observed in the Lau Basin of the western tropical South Pacific
Ocean (WTSP) is fueled by iron (Fe) released from shallow hydrothermal systems …

Speciation and bioavailability of trace metals in water: progress since 1982

GE Batley, SC Apte, JL Stauber - Australian journal of chemistry, 2004 - CSIRO Publishing
The advances in studies of trace metal speciation and bioavailability since Mark Florence's
1982 review of the topic, published in Talanta, have been comprehensively reviewed. While …

Metal speciation in natural waters with emphasis on reduced sulfur groups as strong metal binding sites

DS Smith, RA Bell, JR Kramer - … and Physiology Part C: Toxicology & …, 2002 - Elsevier
The proper application of biotic ligand models to predict metal toxicity depends on accurate
prediction of metal binding to sites on natural organic matter (NOM) which compete with the …

[HTML][HTML] Evidence for copper-binding humic substances in seawater

H Whitby, CMG van den Berg - Marine Chemistry, 2015 - Elsevier
Copper-binding humic substances (Cu–HS) in seawater were determined using a novel
method based on cathodic stripping voltammetry (CSV). Cu–HS adsorb on the mercury (Hg) …