Element‐Ligand Cooperativity with p‐Block Elements
Metal‐ligand cooperativity (MLC) had a tremendous impact on d‐block metal‐mediated
bond activation and homogeneous catalysis. Is this concept translatable to the elements of …
bond activation and homogeneous catalysis. Is this concept translatable to the elements of …
Chemistry of s-, p-and f-block metal complexes with ene-diamido ligands
Y Bai, W Chen, J Li, C Cui - Coordination Chemistry Reviews, 2019 - Elsevier
The α-ene-diamido ligands (the reduced form of α-diimine) have been extensively studied
as supporting ligands for s-, p-and f-block elements over the last several decades. They not …
as supporting ligands for s-, p-and f-block elements over the last several decades. They not …
[图书][B] Early main group metal catalysis: concepts and reactions
S Harder - 2019 - books.google.com
Early Main Group Metal Catalysis gives a comprehensive overview of catalytic reactions in
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …
the presence of group 1 and group 2 metals. Chapters are ordered to reaction type, contain …
Ytterbium and europium complexes of redox-active ligands: searching for redox isomerism
IL Fedushkin, DS Yambulatov, AA Skatova… - Inorganic …, 2017 - ACS Publications
The reaction of (dpp-Bian) EuII (dme) 2 (3)(dpp-Bian is dianion of 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene; dme is 1, 2-dimethoxyethane) with 2, 2 …
diisopropylphenyl) imino] acenaphthene; dme is 1, 2-dimethoxyethane) with 2, 2 …
Low valent Al (II)–Al (II) catalysts as highly active ε-caprolactone polymerization catalysts: Indication of metal cooperativity through DFT studies
OV Kazarina, C Gourlaouen, L Karmazin… - Dalton …, 2018 - pubs.rsc.org
The present study first describes the reactivity of low valent Al (II) and Ga (II) complexes of
the type (dpp-bian) M–M (dpp-bian)(1, M= Al; 2, Ga; dpp-bian2−= 1, 2-bis-(2, 6-iPr2-C6H3) …
the type (dpp-bian) M–M (dpp-bian)(1, M= Al; 2, Ga; dpp-bian2−= 1, 2-bis-(2, 6-iPr2-C6H3) …
Azobenzenyl Calcium Complex: Synthesis and Reactivity Studies of a Ca (I) Synthon
Y Liu, K Zhu, L Chen, S Liu, W Ren - Inorganic Chemistry, 2022 - ACS Publications
Attempted preparation of a low-valent Ca (I) complex by reduction of Ca iodide precursor
[LCaI (THF)] 2 (1)(L=[CH3C (NAr) CHC (CH3) NCH2CH2N (CH3) 2]−, Ar= 2, 6-i Pr2C6H3) …
[LCaI (THF)] 2 (1)(L=[CH3C (NAr) CHC (CH3) NCH2CH2N (CH3) 2]−, Ar= 2, 6-i Pr2C6H3) …
Lanthanum complexes with a diimine ligand in three different redox states
IL Fedushkin, AN Lukoyanov, EV Baranov - Inorganic Chemistry, 2018 - ACS Publications
The reduction of 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene (dpp-Bian) with an
excess of La metal in the presence of iodine (dpp-Bian/I2= 2/1) in tetrahydrofuran (thf) or …
excess of La metal in the presence of iodine (dpp-Bian/I2= 2/1) in tetrahydrofuran (thf) or …
Ligand “brackets” for Ga–Ga bond
IL Fedushkin, AA Skatova, VA Dodonov… - Inorganic …, 2016 - ACS Publications
The reactivity of digallane (dpp-Bian) Ga–Ga (dpp-Bian)(1)(dpp-Bian= 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene) toward acenaphthenequinone (AcQ), sulfur …
diisopropylphenyl) imino] acenaphthene) toward acenaphthenequinone (AcQ), sulfur …
Redox-active ligands–a viable route to reactive main group metal compounds
GG Briand - Dalton Transactions, 2023 - pubs.rsc.org
Anionic redox-active ligands such as o-amidophenolates, catecholates, dithiolenes, 1, 2-
benzendithiolates, 2-amidobenzenethiolates, reduced α-diimines, ferrocenyl and …
benzendithiolates, 2-amidobenzenethiolates, reduced α-diimines, ferrocenyl and …
Gallium Hydrides with a Radical-Anionic Ligand
VG Sokolov, TS Koptseva, MV Moskalev… - Inorganic …, 2017 - ACS Publications
The reaction of Cl2GaH with a sodium salt of the dpp-Bian radical-anion (dpp-Bian•–) Na
(dpp-Bian= 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene) affords paramagnetic …
(dpp-Bian= 1, 2-bis [(2, 6-diisopropylphenyl) imino] acenaphthene) affords paramagnetic …