We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

Organolithium compounds have been at the forefront of synthetic chemistry for over a
century, as they mediate the synthesis of myriads of compounds that are utilised worldwide …

Bismuth catalysis has traditionally relied on the Lewis acidic properties of the element in a
fixed oxidation state. In this paper, we report a series of bismuth complexes that can undergo …

An examination of several catalytic reactions among the group 15 elements is presented.
The connections between the chemistry of the pnictogens can sometimes be challenging …

The controlled release of well‐defined radical species under mild conditions for subsequent
use in selective reactions is an important and challenging task in synthetic chemistry. We …

Recent years have witnessed remarkable advances in radical reactions involving main‐
group metal complexes. This includes the isolation and detailed characterization of main …

Nitroarenes are readily available compounds that are commonly utilized in reductive
processes to form C–NAr bonds via reactive nitrogen intermediates. Recent advances in the …

Organolithiumverbindungen stehen seit mehr als einem Jahrhundert an der Spitze der
Synthesechemie, da sie die Synthese von einer Vielzahl von Verbindungen ermöglichen …

Hydrosilylation and dehydrogenative silylation of alkenes and alkynes are vital
transformations in organic synthesis and have garnered significant attention due to their …

Classically tetraaryl diphosphanes have been synthesized through Wurtz-type reductive
coupling of halophosphanes R2PX or more recently, through the dehydrocoupling of …