Abstract Characterization of structural heterogeneity of liquid solutions and the pursuit of its
nature have been challenging tasks to solution chemists. In the last decade, an emerging …

Chemical processes in solution are influenced by microheterogeneity (MH), where two
liquids seem to be mixed in a macroscopic scale but are microscopically inhomogeneous …

The intermolecular interactions in mixtures of ionic liquids (ILs) of 1-alkyl-3-
methylimidazolium bis (trifluoromethylsulfonyl) amide (C n mimTFSA) and dimethyl sulfoxide …

In this study, we analyzed the species in a model electrolyte consisting of a lithium salt,
lithium bis (trifluoromethane sulfone) imide (LiTFSI), and a widely used neutral solvent …

This paper reports ATR-IR and NIR spectroscopic studies on microheterogeneity in binary
mixtures of methanol with five short chain aliphatic alcohols: ethanol, 1-propanol, 2 …

An electrostatic interaction model of the vibrational frequency changes occurring upon
intermolecular interactions is developed for the Ctriple bondN stretching mode of …

Polar aprotic solvents are considered to act as cosolvents with ionic liquids (ILs) for
cellulose, strengthening the solvating ability of ILs by improving their cellulose solvating …

With a clear enhancement of the apparent resolution of experimentally determined spectra,
excess spectroscopy has been developed as a powerful tool to study solution structures and …

To our best knowledge, this is the first spectroscopic study of small heterogeneity at a
molecular level in binary mixtures of aliphatic and aromatic hydrocarbons. The composition …

Mixtures of acetone, butanol, and ethanol (ABE) are common intermediate products in the
production of biofuels via biomass fermentation. Their separation to yield, for example, bio …