Spontaneous deracemizations

T Buhse, JM Cruz, ME Noble-Teran… - Chemical …, 2021 - ACS Publications
Spontaneous deracemizations is a challenging, multidisciplinary subject in current chirality
research. In the absence of any chiral inductors, an achiral substance or a racemic …

Systems chemistry

G Ashkenasy, TM Hermans, S Otto… - Chemical Society …, 2017 - pubs.rsc.org
Building on our ability to design and synthesise molecules and our understanding of the
noncovalent interactions between these molecules, the chemical sciences are currently …

Prebiotic systems chemistry: new perspectives for the origins of life

K Ruiz-Mirazo, C Briones, A de la Escosura - Chemical reviews, 2014 - ACS Publications
The origin of life is a fascinating, unresolved problem whose deciphering would have
important scientific, epistemological and social implications. Over time, philosophers and …

Autocatalytic models for the origin of biological homochirality

DG Blackmond - Chemical reviews, 2019 - ACS Publications
Autocatalytic models for the emergence of homochirality have been of interest for more than
half a century. The sole experimental example of such an amplifying autocatalytic reaction is …

Crystalline architectures as templates of relevance to the origins of homochirality

I Weissbuch, M Lahav - Chemical Reviews, 2011 - ACS Publications
From the days of Biot1 and Pasteur, 2 when it was recognized that biopolymers are
composed from residues of a single handedness, scientists were puzzled as to the ancestry …

Asymmetric autocatalysis of pyrimidyl alkanol and its application to the study on the origin of homochirality

K Soai, T Kawasaki, A Matsumoto - Accounts of Chemical …, 2014 - ACS Publications
Conspectus Amplification of enantiomeric excess (ee) is a key feature for the chemical
evolution of biological homochirality from the origin of chirality. We describe the amplification …

[HTML][HTML] The protometabolic nature of prebiotic chemistry

N Nogal, M Sanz-Sánchez, S Vela-Gallego… - Chemical Society …, 2023 - pubs.rsc.org
The field of prebiotic chemistry has been dedicated over decades to finding abiotic routes
towards the molecular components of life. There is nowadays a handful of prebiotically …

Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules

K Soai - Proceedings of the Japan Academy, Series B, 2019 - jstage.jst.go.jp
Biological homochirality, such as that of l-amino acids, has been a puzzle with regards to the
chemical origin of life. Asymmetric autocatalysis is a reaction in which a chiral product acts …

Spontaneous mirror symmetry breaking and origin of biological homochirality

JM Ribó, D Hochberg, J Crusats… - Journal of The …, 2017 - royalsocietypublishing.org
Recent reports on both theoretical simulations and on the physical chemistry basis of
spontaneous mirror symmetry breaking (SMSB), that is, asymmetric synthesis in the absence …

Autocatalyses

R Plasson, A Brandenburg, L Jullien… - The Journal of Physical …, 2011 - ACS Publications
Autocatalysis is a fundamental concept, used in a wide range of domains. From the most
general definition of autocatalysis, that is, a process in which a chemical compound is able …