Remote functionalization through alkene isomerization

A Vasseur, J Bruffaerts, I Marek - Nature chemistry, 2016 - nature.com
Exploiting the reactivity of one functional group within a molecule to generate a reaction at a
different position is an ongoing challenge in organic synthesis. Effective remote …

Long-chain aliphatic polymers to bridge the gap between semicrystalline polyolefins and traditional polycondensates

F Stempfle, P Ortmann, S Mecking - Chemical reviews, 2016 - ACS Publications
Other than their established short-chain congeners, polycondensates based on long-chain
difunctional monomers are often dominated by the long methylene sequences of the repeat …

[HTML][HTML] Plant oils: The perfect renewable resource for polymer science?!

LM de Espinosa, MAR Meier - European Polymer Journal, 2011 - Elsevier
Already for a long time, plant oils and their derivatives have been used by polymer chemists
due to their renewable nature, world wide availability, relatively low price, and their rich …

Asymmetric Markovnikov hydroaminocarbonylation of alkenes enabled by palladium-monodentate phosphoramidite catalysis

YH Yao, HY Yang, M Chen, F Wu, XX Xu… - Journal of the …, 2020 - ACS Publications
A palladium-catalyzed asymmetric Markovnikov hydroaminocarbonylation of alkenes with
anilines has been developed for the atom-economical synthesis of 2-substituted …

Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes

JS Bair, Y Schramm, AG Sergeev, E Clot… - Journal of the …, 2014 - ACS Publications
We report a series of hydroarylations of unactivated olefins with trifluoromethyl-substituted
arenes that occur with high selectivity for the linear product without directing groups on the …

Rhodium-catalyzed, remote terminal hydroarylation of activated olefins through a long-range deconjugative isomerization

AJ Borah, Z Shi - Journal of the American Chemical Society, 2018 - ACS Publications
The Rh-catalyzed, remote terminal hydroarylation of active olefins at the C7-position of
indoles and the ortho-position of indolines and anilines with the appropriate choice of a NP t …

Towards resource efficient chemistry: tandem reactions with renewables

A Behr, AJ Vorholt, KA Ostrowski, T Seidensticker - Green Chemistry, 2014 - pubs.rsc.org
In an economically expanding world new sustainable concepts have to be developed in
order to overcome growing problems of resource availability. Merging different “Green …

Highly active and efficient catalysts for alkoxycarbonylation of alkenes

K Dong, X Fang, S Gülak, R Franke… - Nature …, 2017 - nature.com
Carbonylation reactions of alkenes constitute the most important industrial processes in
homogeneous catalysis. Despite the tremendous progress in this transformation, the …

Cashew nut shell: a potential bio-resource for the production of bio-sourced chemicals, materials and fuels

J Mgaya, GB Shombe, SC Masikane, S Mlowe… - Green …, 2019 - pubs.rsc.org
Exploitation of agricultural waste as green starting materials to produce various valuable
products is attracting the attention of academic, industrial and other practitioners. Cashew …

Magic of Alpha: The Chemistry of a Remarkable Bidentate Phosphine, 1,2-Bis(di-tert-butylphosphinomethyl)benzene

J Vondran, MRL Furst, GR Eastham… - Chemical …, 2021 - ACS Publications
The bidentate phosphine ligand 1, 2-bis (di-tert-butylphosphinomethyl) benzene (1, 2-
DTBPMB) has been reported over the years as being one of, if not the, best ligands for …