Recent advances in reactions of azides

D Huang, G Yan - Advanced Synthesis & Catalysis, 2017 - Wiley Online Library
Azides are important intermediates in organic synthesis. They can function as precursors to
form amines, amides, quinolones, pyridines, triazoles, amidines, indoles, and so on …

The Rich Chemistry Resulting from the 1, 3‐Dipolar Cycloaddition Reactions of Enamines and Azides

VA Bakulev, T Beryozkina, J Thomas… - European Journal of …, 2018 - Wiley Online Library
Enamines exhibit exceptionally high reactivity in their 1, 3‐dipolar cycloaddition reactions
with azides in comparison with other dipolarophiles. This review includes the reactions of …

Metal-free syntheses of N-functionalized and NH-1, 2, 3-triazoles: an update on recent developments

T Opsomer, W Dehaen - Chemical Communications, 2021 - pubs.rsc.org
An overview of the latest developments in the metal-free synthesis of non-benzo-fused N-
functionalized and NH-1, 2, 3-triazoles is provided in this feature article. Synthetic studies …

A general metal-free route towards the synthesis of 1, 2, 3-triazoles from readily available primary amines and ketones

J Thomas, S Jana, J John, S Liekens… - Chemical …, 2016 - pubs.rsc.org
An unprecedented approach that enables the direct and selective preparation of 1, 5-
disubstituted 1, 2, 3-triazoles from abundantly available building blocks such as primary …

A single-step acid catalyzed reaction for rapid assembly of NH-1, 2, 3-triazoles

J Thomas, S Jana, S Liekens, W Dehaen - Chemical Communications, 2016 - pubs.rsc.org
NH-1, 2, 3-Triazole moieties are a part of the design of various biologically active
compounds, pharmaceutical agents and functional materials. Unfortunately, the applications …

Microwave-Assisted, Metal-and Azide-Free Synthesis of Functionalized Heteroaryl-1, 2, 3-triazoles via Oxidative Cyclization of N-Tosylhydrazones and Anilines

ZZ Gulledge, DP Duda, DA Dixon… - The Journal of Organic …, 2022 - ACS Publications
As the search for competent soft-Lewis basic complexants for separations continues to
evolve toward identification of a chemoselective moiety for speciation of the minor actinides …

Three‐Component Coupling of α‐Trifluoromethyl Carbonyls, Azides and Amines for the Regioselective Synthesis of 1, 4, 5‐Trisubstituted 1, 2, 3‐Triazoles

G Gao, Kuantao, Mao, L Lv, Z Li - Advanced Synthesis & …, 2022 - Wiley Online Library
A metal‐free three‐component coupling of α‐CF3 carbonyls, azides and amines for the
regioselective synthesis of 1, 4, 5‐trisubstituted 1, 2, 3‐triazoles in the air is established …

Regioselective Synthesis of N2-Aryl 1,2,3-Triazoles via Electro-oxidative Coupling of Enamines and Aryldiazonium Salts

M Baidya, S Mallick, S De Sarkar - Organic Letters, 2022 - ACS Publications
An efficient synthetic route for the construction of N 2-aryl 1, 2, 3-triazoles is reported via
sequential C–N bond formation and electro-oxidative N–N coupling under metal-free …

[3+ 3] Cycloaddition of Azides with in Situ Formed Azaoxyallyl Cations To Synthesize 1, 2, 3, 4-Tetrazines

X Xu, K Zhang, P Li, H Yao, A Lin - Organic letters, 2018 - ACS Publications
A formal [3+ 3] cycloaddition reaction between azides and in situ formed azaoxyallyl cations
has been realized. This reaction provided an efficient and practical pathway to synthesize 1 …

Room-temperature organocatalytic cycloaddition of azides with β-keto sulfones: toward sulfonyl-1, 2, 3-triazoles

MT Saraiva, GP Costa, N Seus, RF Schumacher… - Organic …, 2015 - ACS Publications
Organocatalytic enamine–azide [3+ 2] cycloadditions between β-keto sulfones and aryl
azides can be performed at room temperature in good to excellent yields of products in the …