Complexes of Ni (I): a “rare” oxidation state of growing importance
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …
well as in chemical applications such as the catalytic transformation of organic substrates …
Stable Two-Coordinate, Open-Shell (d1–d9) Transition Metal Complexes
PP Power - Chemical Reviews, 2012 - ACS Publications
1. INTRODUCTION Stable, open-shell (d1− d9) transition metal complexes in which the
metal is two-coordinate or quasi-two-coordinate are among the rarest and least investigated …
metal is two-coordinate or quasi-two-coordinate are among the rarest and least investigated …
Binding of dinitrogen to an iron–sulfur–carbon site
Nitrogenases are the enzymes by which certain microorganisms convert atmospheric
dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher …
dinitrogen (N2) to ammonia, thereby providing essential nitrogen atoms for higher …
Cooperative catalytic activation of Si− H bonds by a polar Ru− S bond: regioselective low-temperature C− H silylation of indoles under neutral conditions by a Friedel …
HFT Klare, M Oestreich, J Ito, H Nishiyama… - Journal of the …, 2011 - ACS Publications
Merging cooperative Si− H bond activation and electrophilic aromatic substitution paves the
way for C-3-selective indole C− H functionalization under electronic and not conventional …
way for C-3-selective indole C− H functionalization under electronic and not conventional …
Cooperative catalysis at metal–sulfur bonds
L Omann, CDF Königs, HFT Klare… - Accounts of Chemical …, 2017 - ACS Publications
Conspectus Cooperative catalysis has attracted tremendous attention in recent years,
emerging as a key strategy for the development of novel atom-economic and …
emerging as a key strategy for the development of novel atom-economic and …
[图书][B] The crystal as a supramolecular entity
GR Desiraju - 2008 - books.google.com
Supramolecular chemistry involves the study and synthesis of very large molecules which
are used in complex chemical reactions, and have great potential in areas such as …
are used in complex chemical reactions, and have great potential in areas such as …
Isolation of a stable, acyclic, two-coordinate silylene
BD Rekken, TM Brown, JC Fettinger… - Journal of the …, 2012 - ACS Publications
The synthesis and characterization of a stable, acyclic two-coordinate silylene, Si (SArMe6)
2 [ArMe6= C6H3-2, 6 (C6H2-2, 4, 6-Me3) 2], by reduction of Br2Si (SArMe6) 2 with a …
2 [ArMe6= C6H3-2, 6 (C6H2-2, 4, 6-Me3) 2], by reduction of Br2Si (SArMe6) 2 with a …
Electronically unsaturated three-coordinate chloride and methyl complexes of iron, cobalt, and nickel
PL Holland, TR Cundari, LL Perez… - Journal of the …, 2002 - ACS Publications
Three-coordinate organometallic complexes are rare, especially with the prototypical methyl
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …
ligand. Using a hindered, rigid bidentate ligand (L), it is possible to create 12-electron …
C− H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene
Y Ohki, T Hatanaka, K Tatsumi - Journal of the American Chemical …, 2008 - ACS Publications
Half-sandwich iron complexes of N-heterocyclic carbenes, Cp* Fe (LR) Cl (2a; LMes= 1, 3-
dimesityl-imidazol-2-ylidene, 2b; LiPr= 1, 3-diisopropyl-4, 5-dimethylimidazol-2-ylidene …
dimesityl-imidazol-2-ylidene, 2b; LiPr= 1, 3-diisopropyl-4, 5-dimethylimidazol-2-ylidene …
Some highlights from the development and use of bulky monodentate ligands
PP Power - Journal of organometallic chemistry, 2004 - Elsevier
The development of bulky monodentate alkoxide, chalcogenolate (ER, E= S, Se or Te),
amide, pnictide (ER2= N, P, As), alkyl, aryl and silyl ligands is briefly surveyed. These …
amide, pnictide (ER2= N, P, As), alkyl, aryl and silyl ligands is briefly surveyed. These …