Expeditious Synthesis of Gwanakoside A and the Chloronaphthol Glycoside Congeners

Y Cheng, Y Xia, Z Yuan, H Li, J Wang, Y Wang… - Organic …, 2024 - ACS Publications
The synthesis of gwanakoside A, a chlorinated naphthol bis-glycoside, and its analogues
was achieved through stepwise chlorination and donor-equivalent controlled regioselective …

Recent Advances in Chlorination: Novel Reagents and Methods from the Last Decade

IC Vogel, DCGA Pinto, NR Candeias - SynOpen, 2024 - thieme-connect.com
Chlorinated compounds are vital in organic synthesis, impacting nucleophilic substitutions, β-
elimination, and CH acidity. This review highlights recent advances in (hetero) arene …

Regioselective synthesis of 2-aminophenols from N-arylhydroxylamines

Z Gao, Z Hou, H Gao - Organic & Biomolecular Chemistry, 2024 - pubs.rsc.org
A novel strategy for the synthesis of 2-aminophenols in the absence of metals and oxidants
was described. The 2-aminophenols were efficiently obtained through a cascade [3, 3] …

Regioselective Organocatalyzed Monochlorination of Arenes with Electrophilic Chlorosulfoniums

A Garay‐Talero, P Acosta‐Guzmán… - Advanced Synthesis …, 2023 - Wiley Online Library
This manuscript presents a regioselective chlorination of arenes, yielding almost exclusively
the monochlorinated product. It tolerates free hydroxy groups, 1°, 2° and 3° amines, and …