Design of collective motions from synthetic molecular switches, rotors, and motors

D Dattler, G Fuks, J Heiser, E Moulin, A Perrot… - Chemical …, 2019 - ACS Publications
Precise control over molecular movement is of fundamental and practical importance in
physics, biology, and chemistry. At nanoscale, the peculiar functioning principles and the …

The halogen bond

G Cavallo, P Metrangolo, R Milani, T Pilati… - Chemical …, 2016 - ACS Publications
The halogen bond occurs when there is evidence of a net attractive interaction between an
electrophilic region associated with a halogen atom in a molecular entity and a nucleophilic …

Halogen-bonded shape memory polymers

H Guo, R Puttreddy, T Salminen, A Lends… - Nature …, 2022 - nature.com
Halogen bonding (XB), a non-covalent interaction between an electron-deficient halogen
atom and a Lewis base, is widely adopted in organic synthesis and supramolecular crystal …

Halogen bonding in polymer science: from crystal engineering to functional supramolecular polymers and materials

G Berger, J Soubhye, F Meyer - Polymer Chemistry, 2015 - pubs.rsc.org
Halogen bonding (XB) is commonly defined as a non-covalent bond where halogen atoms
(X= Cl, Br, I) function as electron acceptors. As an analogue of hydrogen bonding, halogen …

Programmable and Self‐Healable Liquid Crystal Elastomer Actuators Based on Halogen Bonding

H Guo, C Liang, TP Ruoko, H Meteling… - Angewandte Chemie …, 2023 - Wiley Online Library
Shape‐changing polymeric materials have gained significant attention in the field of
bioinspired soft robotics. However, challenges remain in versatilizing the shape‐morphing …

Halogen bonding in polymer science: towards new smart materials

R Kampes, S Zechel, MD Hager, US Schubert - Chemical Science, 2021 - pubs.rsc.org
The halogen bond is a special non-covalent interaction, which can represent a powerful tool
in supramolecular chemistry. Although the halogen bond offers several advantages …

Halogen‐bonded hole‐transport material suppresses charge recombination and enhances stability of perovskite solar cells

L Canil, J Salunke, Q Wang, M Liu… - Advanced Energy …, 2021 - Wiley Online Library
Interfaces play a crucial role in determining perovskite solar cells,(PSCs) performance and
stability. It is therefore of great importance to constantly work toward improving their design …

Halogen bonding beyond crystals in materials science

M Saccone, L Catalano - The Journal of Physical Chemistry B, 2019 - ACS Publications
Halogen bonding has recently gained well deserved attention in present-day research for its
importance in many fields of supramolecular science and crystal engineering. Although …

Supramolecular macrocycles reversibly assembled by TeO chalcogen bonding

PC Ho, P Szydlowski, J Sinclair, PJW Elder… - Nature …, 2016 - nature.com
Organic molecules with heavy main-group elements frequently form supramolecular links to
electron-rich centres. One particular case of such interactions is halogen bonding. Most …

Supramolecular design principles for efficient photoresponsive polymer–azobenzene complexes

J Vapaavuori, CG Bazuin, A Priimagi - Journal of Materials Chemistry …, 2018 - pubs.rsc.org
Noncovalent binding of azobenzenes to polymers allows harnessing light-induced
molecular-level motions (photoisomerization) for inducing macroscopic effects, including …