A three-dimensional walnut-like Zn-based MOF microsphere system was designed and
synthesized via hydrothermal reaction of zinc salt with 4, 6-diamino-2-pyrimidinethiol as a …

Zn-catalysed reactions are ubiquitously important due to their inexpensive, generally less
toxic and atom-economic nature. According to the modern criteria of sustainability, their use …

The construction of the SCF3‐containing 1, 1‐diaryl tertiary carbon stereocenters with high
enantioselectivities is reported via a nickel‐catalyzed asymmetric C− C coupling strategy …

The application of dinuclear zinc catalysts in a dearomatization reaction has been
developed. Catalytic asymmetric dearomatization [3+ 2] annulations of 2‐nitrobenzofurans …

This review collects the recent advances in the field of enantioselective zinc-catalyzed
transformations, covering the literature since the beginning of 2015, illustrating the power of …

The nickel-catalyzed reductive cross-coupling reaction of acyl chloride with racemic
secondary α-trifluoromethyl bromide has been developed. By this chemistry, a series of …

Commercially available compound ZnEt2 acts as an efficient precatalyst for the solvent-free
hydrophosphinations of heterocumulenes using Ph2PH as reagent. As far as we knew, this …

A practical protocol for the stereodivergent synthesis of 2-alkylidene-1, 3-N, X-heterocycles
(X= O, S, NR) from the reactions of α-CF 3 carbonyls and bis-nucleophiles has been …

The enantioselective mechanism of the Mannich reaction with fluorinated aromatic ketones
catalyzed by Zn/prophenol was examined using B3LYP density functional theory. Four …

Herein, we report a strategically novel synthetic protocol for the efficient construction of α-
trifluoromethyl-β-amino ketone and α-sulfonyl-β-amino ketone derivatives. 4-Isoxazoline is …