Alkaline‐based electrochemical devices, such as anion exchange membrane (AEM) fuel
cells and electrolyzers, are receiving increasing attention. However, while the catalysts and …

The lithium-mediated nitrogen reduction reaction (LiNRR) produces ammonia in ambient
conditions. This electrochemical pathway is dependent on a catalytic solid–electrolyte …

Ammonia is of great importance in fertilizer production and chemical synthesis. It can also
potentially serve as a carbon-free energy carrier for a future hydrogen economy. Motivated …

The solid-electrolyte interphase (SEI) is often invoked to rationalize trends observed during
lithium-mediated electrochemical ammonia synthesis (LiMEAS), but quantitative analysis of …

Li-mediated ammonia synthesis is, thus far, the only electrochemical method for
heterogeneous decentralized ammonia production. The unique selectivity of the solid …

The Li-mediated nitrogen reduction enables practical synthesis of ammonia, but its energy
efficiency is limited by the Li0/+ redox potential. To improve on this, a mediator with a more …

The performance of the Li-mediated ammonia synthesis has progressed dramatically since
its recent reintroduction. However, fundamental understanding of this reaction is slower …

The lithium-mediated system catalyzes nitrogen to ammonia under ambient conditions.
Herein we discover that trace amount of water as an electrolyte additive─ in contrast to prior …

Alkali ions, major components at the electrode–electrolyte interface, are crucial to
modulating reaction activity and selectivity of catalyst materials. However, the underlying …

Green ammonia (NH3), made by using renewable electricity to split nearly limitless nitrogen
(N2) molecules, is a vital platform molecule and an ideal fuel to drive the sustainable …