Trivalent aluminium compounds are well known for their reactivity as Lewis
acids/electrophiles, a feature that is exploited in many pharmaceutical, industrial and …

Synthetic routes to lithium, magnesium, and zinc aluminyl complexes are reported, allowing
for the first structural characterization of an unsupported lithium–aluminium bond …

We present facile access to an alumaborane species with electron precise Al− B σ‐bond.
The reductive rearrangement of 1‐(AlI2), 8‐(BMes2) naphthalene (Mes= 2, 4, 6‐Me3C6H2) …

Heterodiatomic multiple bonds have never been observed within Group 13. Herein, we
disclose a method that generates [(CAAC) PhB= AlCp3t](1), a complex featuring π bonding …

The seven‐membered cyclic potassium alumanyl species,[{SiNMes} AlK] 2 [{SiNMes}={
CH2SiMe2N (Mes)} 2; Mes= 2, 4, 6‐Me3C6H2], which adopts a dimeric structure supported …

The pentaaryl borole (Ph* C) 4BXylF [Ph*= 3, 5‐tBu2 (C6H3); XylF= 3, 5‐(CF3) 2 (C6H3)]
reacts with low‐valent Group 13 precursors AlCp* and GaCp* by two divergent routes. In the …

The so far poorly understood factors controlling the complete meta‐selectivity observed in
the C− H activation reactions of alkylarenes promoted by aluminyl anions have been …

Es wird ein einfacher Zugang zu einer Alumaboran‐Spezies mit elektronenpräziser Al− B σ‐
Bindung vor‐gestellt. Die reduktive Umlagerung von 1‐(AlI2), 8‐(BMes2)‐Naphthalin (Mes …

The parent borylene (CAAC)(Me3P) BH, 1 (CAAC= cyclic alkyl (amino) carbene), acts both
as a Lewis base and one‐electron reducing agent towards group 13 trichlorides (ECl3, E …

Verbindungen mit heterodiatomarer Mehrfachbindung zwischen Gruppe‐13‐Elementen
sind bislang unbekannt. In dieser Zuschrift berichten wir über eine Darstellungsmethode von …