Anomeric effect, hyperconjugation and electrostatics: Lessons from complexity in a classic stereoelectronic phenomenon
Understanding the interplay of multiple components (steric, electrostatic, stereoelectronic,
dispersive, etc.) that define the overall energy, structure, and reactivity of organic molecules …
dispersive, etc.) that define the overall energy, structure, and reactivity of organic molecules …
Molecular crowding electrolytes for high-voltage aqueous batteries
Developing low-cost and eco-friendly aqueous electrolytes with a wide voltage window is
critical to achieve safe, high-energy and sustainable Li-ion batteries. Emerging approaches …
critical to achieve safe, high-energy and sustainable Li-ion batteries. Emerging approaches …
Molecular crowding effect in aqueous electrolytes to suppress hydrogen reduction reaction and enhance electrochemical nitrogen reduction
The H2 evolution reaction (HER), one of the most intractable issues for the electrochemical
N2 reduction reaction (NRR), seriously hinders NH3 production selectivity and yield rate …
N2 reduction reaction (NRR), seriously hinders NH3 production selectivity and yield rate …
Evidence for European presence in the Americas in ad 1021
Transatlantic exploration took place centuries before the crossing of Columbus. Physical
evidence for early European presence in the Americas can be found in Newfoundland …
evidence for early European presence in the Americas can be found in Newfoundland …
Out-of-the-box deep learning prediction of pharmaceutical properties by broadly learned knowledge-based molecular representations
Successful deep learning critically depends on the representation of the learned objects.
Recent state-of-the-art pharmaceutical deep learning models successfully exploit graph …
Recent state-of-the-art pharmaceutical deep learning models successfully exploit graph …
Covalent Surface Modification of Ti3C2Tx MXene with Chemically Active Polymeric Ligands Producing Highly Conductive and Ordered Microstructure Films
JT Lee, BC Wyatt, GA Davis Jr, AN Masterson… - ACS …, 2021 - ACS Publications
As interest continues to grow in Ti3C2T x and other related MXenes, advancement in
methods of manipulation of their surface functional groups beyond synthesis-based surface …
methods of manipulation of their surface functional groups beyond synthesis-based surface …
A critical review of the physicochemical properties of lignosulfonates: chemical structure and behavior in aqueous solution, at surfaces and interfaces
J Ruwoldt - Surfaces, 2020 - mdpi.com
Lignosulfonates are bio-based surfactants and specialty chemicals, which are generated by
breaking the near-infinite lignin network during sulfite pulping of wood. Due to their …
breaking the near-infinite lignin network during sulfite pulping of wood. Due to their …
Metal-catalyzed plastic depolymerization
Polymers have become an indispensable part of our daily lives, and today we produce
around 370 MT of plastic per year. Only about 20% of it is being recycled, and the rest, 80 …
around 370 MT of plastic per year. Only about 20% of it is being recycled, and the rest, 80 …
New wine in old bottles: Prolonging room‐temperature phosphorescence of crown ethers by supramolecular interactions
Supramolecular macrocyclic hosts have long been used in smart materials. However, their
triplet emission and regulation at crystal level is rarely studied. Herein, ultralong and …
triplet emission and regulation at crystal level is rarely studied. Herein, ultralong and …