Sulfoximine and its congeners are a versatile class of structural motifs widely found in a
plethora of pharmaceutical compounds and crop protection industries due to their …

Ruthenium complexes are well known as remarkable pre-catalysts for challenging C–H
bond functionalizations. Combining them with other types of chemical reactions in a tandem …

Ru (II)-catalyzed enantioselective C–H activation/hydroarylation has been developed for the
first time, allowing for highly enantioselective synthesis of indoline derivatives via catalytic C …

A ruthenium (II)‐catalyzed asymmetric intramolecular hydroarylation assisted by a chiral
transient directing group has been developed. A series of 2, 3‐dihydrobenzofurans bearing …

Developed herein is a chiral sulfoximine-enabled Ru (II)-catalyzed asymmetric C–H
activation/functionalization involving intramolecular hydroarylation and functionalization …

Multiple C− H bond functionalizations promptly install diverse groups on the molecular
framework and consequently fabricate complex molecular entities. This review briefly …

An unconventional cobalt (III)-catalyzed one-pot domino double annulation of aryl
thioamides with unactivated alkynes is presented. Sulfur (S), nitrogen (N), and o, o′-C–H …

Direct difunctionalization of chemically distinct ortho-and peri-C–H bonds of fused hetero
(arenes) is illustrated through an unusual one-pot domino {[4+ 2] & [5+ 2]} double annulation …

Transition‐metal‐catalyzed direct C− H bond activation reactions have been embraced as a
powerful synthetic tool to access diverse functionalized arenes. However, site‐selective …

A highly efficient process for Rh (III)-catalyzed C–H activation/annulation of N-
iminopyridinium ylides with alkynes and diazo compounds has been realized, providing a …