This review serves to document advances in the synthesis, versatile bonding, and reactivity
of molecular main group metal hydrides within Groups 1, 2, and 12–16. Particular attention …

Hydroelementation enables a facile reduction or functionalization of several unsaturated
systems, and thus activation of such bonds like B–H and Si–H is a powerful synthetic tool …

We report a strategy to develop heterogeneous single‐site enantioselective catalysts based
on naturally occurring amino acids and earth‐abundant metals for eco‐friendly asymmetric …

This review highlights the hydroelementation reactions of conjugated and separated diynes,
which depending on the process conditions, catalytic system, as well as the type of reagents …

The development of homogeneous iron catalysts has been a prolific research field in recent
years. Many catalytic reactions are no longer limited to noble metals. The use of N …

Organoselenium compounds have been used extensively as building blocks for the
development of catalysts for several chemical transformations during the last two decades …

The development of highly efficient and enantioselective heterogeneous catalysts based on
earth-abundant elements and inexpensive chiral ligands is essential for environment …

Over the past decades, organometallic complexes with precious elements, such as
ruthenium and iridium, are widely used as visible‐light photoredox catalysts. Recently, more …

Tris [N, N-bis (trimethylsilyl) amido] lanthanum (LaNTMS) is an efficient, highly active, and
selective homogeneous catalyst for ester reduction with pinacolborane (HBpin). Alkyl and …

Siloxanes and silanols containing Si–H units are important building blocks for the synthesis
of functionalized siloxane materials, and their synthesis is a current challenge. Herein, we …