Click chemistry strategies for the accelerated synthesis of functional macromolecules

Z Geng, JJ Shin, Y Xi, CJ Hawker - Journal of Polymer Science, 2021 - Wiley Online Library
Click chemistry is one of the most powerful strategies for constructing polymeric soft
materials with precise control over architecture and functionality. In this review, we provide a …

Nucleophilic Thiol-yne reaction in Macromolecular Engineering: From synthesis to applications

O Daglar, S Luleburgaz, E Baysak, US Gunay… - European Polymer …, 2020 - Elsevier
The developments in synthetic polymer chemistry have devoted to meet the huge demand
required to create efficient, high yield, and operationally simple chemical methods that can …

3D printing hierarchically nano‐ordered structures

B Weidinger, G Yang, N von Coelln, H Nirschl… - Advanced …, 2023 - Wiley Online Library
Natural materials are composed of a limited number of molecular building blocks and their
exceptional properties are governed by their hierarchical structure. However, this level of …

The para-fluoro-thiol reaction as an efficient tool in polymer chemistry

G Delaittre, L Barner - Polymer Chemistry, 2018 - pubs.rsc.org
In the current contribution, we discuss the application and potential of the versatile para-
fluoro-thiol reaction in the context of synthesis and modification of polymers and materials …

An emerging post‐polymerization modification technique: The promise of thiol‐para‐fluoro click reaction

S Agar, E Baysak, G Hizal, U Tunca… - Journal of Polymer …, 2018 - Wiley Online Library
Post‐polymerization modification (PPM) of polymers is extremely beneficial in terms of
designing brand new synthetic pathways toward functional complex polymers. Fortunately …

Synergy of advanced experimental and modeling tools to underpin the synthesis of static step-growth-based networks involving polymeric precursor building blocks

L De Keer, F Cavalli, D Estupiñán, AJD Krüger… - …, 2021 - ACS Publications
The strength of combining experimental design and advanced kinetic Monte Carlo (kMC)
modeling to understand step-growth network synthesis, commencing with a linear/star …

An in-depth analysis approach enabling precision single chain nanoparticle design

J Engelke, BT Tuten, R Schweins, H Komber… - Polymer …, 2020 - pubs.rsc.org
The synthesis of single chain nanoparticles (SCNPs) is a vibrant field in macromolecular
science, enabled by a rich variety of synthetic strategies to induce macromolecular chain …

Para-Fluoro Postpolymerization Chemistry of Poly(pentafluorobenzyl methacrylate): Modification with Amines, Thiols, and Carbonylthiolates

JM Noy, AK Friedrich, K Batten, MN Bhebhe… - …, 2017 - ACS Publications
A methacrylic polymer undergoing highly efficient para-fluoro substitution reactions is
presented. A series of well-defined poly (2, 3, 4, 5, 6-pentafluorobenzyl methacrylate) …

Azide–para-Fluoro Substitution on Polymers: Multipurpose Precursors for Efficient Sequential Postpolymerization Modification

JM Noy, Y Li, W Smolan, PJ Roth - Macromolecules, 2019 - ACS Publications
The 2, 3, 4, 5, 6-pentafluorobenzyl group has become a popular reactive functionality in
polymer chemistry because of its high susceptibility to para-fluoro substitution with thiols …

Reactive precursor particles as synthetic platform for the generation of functional nanoparticles, nanogels, and microgels

A Gruber, L Navarro, D Klinger - Advanced Materials Interfaces, 2020 - Wiley Online Library
Precise control of the chemical functionality of polymer nanoparticles is a key requirement in
tailoring their (dynamic) colloidal properties toward advanced applications. However, current …