Catalytic System for Aerobic Oxidation That Simultaneously Functions as Its Own Redox Buffer

X Lu, T Cheng, YV Geletii, CL Hill - Inorganic Chemistry, 2023 - ACS Publications
The control of the solution electrochemical potential as well as pH impacts products in redox
reactions, but the former gets far less attention. Redox buffers facilitate the maintenance of …

A kinetic study of the oxidations of 2-mercaptoethanol and 2-mercaptoethylamine by heteropoly 11-tungsto-1-vanadophosphate in aqueous acidic medium

T Shanmugaprabha, K Selvakumar… - Transition Metal …, 2016 - Springer
The kinetics of oxidation of 2-mercaptoethanol and 2-mercaptoethylamine by the heteropoly
11-tungsto-1-vanadophosphate anion,[PV VW 11 O 40] 4−, have been studied …

Vanadium (V)-substituted Keggin-type heteropolyoxotungstophosphates as electron transfer and antimicrobial agents: oxidation of glutathione and sensitization of …

P Sami, TD Anand, M Premanathan… - Transition Metal …, 2010 - Springer
Glutathione (GSH) undergoes facile electron transfer with vanadium (V)-substituted Keggin-
type heteropolyoxometalates, PV^ VW _ 1 1 O _ 4 0^ 4-(HPA1) and PV^ VV^ VW _ 1 0 O _ 4 …

POM ‐based Electrocatalysts for l ‐Cysteine and NADH Oxidation

I Mbomekallé, AL Teillout… - Applied Polyoxometalate …, 2025 - Wiley Online Library
On the one hand, both l‐cysteine (Cys) and nicotinamide adenine dinucleotide (NADH) are
molecules of great relevance in biological systems, being involved in several metabolic …

Proton-coupled electron transfer reactions: kinetic studies on the oxidation of dihydroxybenzenes by heteropoly 10-tungstodivanadophosphate in aqueous acidic …

T Shanmugaprabha, K Selvakumar… - Transition Metal …, 2015 - Springer
Kinetic studies on the oxidation of hydroquinone and catechol by the heteropoly 10-
tungstodivanadophosphate anion,[PV VVVW 10 O 40] 5−, have been carried out in aqueous …

Activation-controlled outer-sphere electron transfer reactions: reduction of heteropoly 11-tungstovanadophosphate and heteropoly 10-tungstodivanado phosphate by …

P Sami, N Mariselvi, K Venkateshwari… - Transition Metal …, 2010 - Springer
The kinetics of reduction of heteropoly 11-tungstovanadophosphate,[PV VW 11 O 40]
4−,(HPA1) and heteropoly 10-tungstodivanadophosphate,[PV VVVW 10 O 40] 5−,(HPA2) by …

Studies on electron transfer reactions: oxidation of phenol and ring-substituted phenols by heteropoly 11-tungstophosphovanadate (V) in aqueous acidic medium

M Vairalakshmi, V Raj, P Sami… - Transition Metal Chemistry, 2011 - Springer
The kinetics of oxidation of phenol and a few ring-substituted phenols by heteropoly 11-
tungstophosphovanadate (V),[PV VW 11 O 40] 4−(HPA) have been studied …

[PDF][PDF] Kinetics and Mechanism of Catalyzed Oxidation of L-Cysteine by Salen Schiff Base Complexes of Co (III), Fe (III) and Cr (III)

HM Abdel-Halim, HM Baker, AI Alhmaideen… - International Journal of …, 2021 - academia.edu
Kinetics of oxidation of L-cysteine by new series of substituted ONNO-donor salen-type
Schiff base complexes of general formula [MIII (L) Cl](M= Co, Fe, Cr; L= Schiff base ligand) …

[PDF][PDF] Thangamariyappan Shanmugaprabha, Karuppaiah Selvakumar, Murugesan Vairalakshmi, Kasi Rajasekaran &

P Sami - Transition Met Chem, 2015 - researchgate.net
Kinetic studies on the oxidation of hydroquinone and catechol by the heteropoly 10-
tungstodivanadophosphate anion,[PVVVVW10O40] 5-, have been carried out in aqueous …

Kinetics of Oxidation of L-Cysteine by Cobalt (III), Iron (III), and Chromium (III) Complexes of Salicylaldiminato Ligands

H Abdel-Halim - Jordan Journal of Chemistry (JJC), 2012 - jjc.yu.edu.jo
Kinetics of oxidation of L-cysteine by penta-coordinated Co (III), Fe (III), and Cr (III)
complexes of salicylaldiminato ligands have been studied in aqueous solutions. Metal …