The Deuterated “Magic Methyl” Group: A Guide to Site‐Selective Trideuteromethyl Incorporation and Labeling by Using CD3 Reagents

J Steverlynck, R Sitdikov… - Chemistry–A European …, 2021 - Wiley Online Library
In the field of medicinal chemistry, the precise installation of a trideuteromethyl group is
gaining ever‐increasing attention. Site‐selective incorporation of the deuterated “magic …

Ion-neutral complexes

RD Bowen - Accounts of chemical research, 1991 - ACS Publications
An ion-neutral complex (INC) consists of an incipient ion coordinated to a putative neutral.
The two com-ponents of the INC are not connected by a normal co-valent bond, but …

Gas-phase analogs of cage effects

DJ McAdoo, TH Morton - Accounts of chemical research, 1993 - ACS Publications
When a molecule dissociates, three types of transport phenomena compete with
recombination of the fragments. Translational diffusion carries the cleavage products into the …

Density functional theory and mass spectrometry of phthalate fragmentations mechanisms: modeling hyperconjugated carbocation and radical cation complexes with …

YA Jeilani, BH Cardelino… - Journal of the American …, 2011 - ACS Publications
This is the first ab initio study of the energetics of the fragmentation mechanisms of
phthalate, by mass spectrometry, leading to protonated phthalic anhydride (m/z 149) …

Systematic MALDI‐TOF CID investigation on different substituted mPEG 2000

K Knop, BO Jahn, MD Hager… - Macromolecular …, 2010 - Wiley Online Library
Abstract Methoxy poly (ethylene glycol) 2000 (mPEG 2000) samples were substituted via
esterification reactions to convert the hydroxyl end group of the mPEG into potential initiators …

The distonic ion ˙CH2CH2CO+ and its formation from ionized cyclopentanone

JC Traeger, CE Hudson… - Organic mass …, 1989 - Wiley Online Library
Collisional activation decomposition (CAD) spectra are interpreted as indicating that
formation of˙ CH2CH2CO+ (1) from ionized cyclopentanone, succinic anhydride arid …

Oxido-molybdenum complexes obtained by Cl/O interchange between MoCl 5 and carboxylic acids: a crystallographic, spectroscopic and computational study

M Bortoluzzi, F Marchetti, G Pampaloni… - Dalton Transactions, 2014 - pubs.rsc.org
The direct interaction of MoCl5 with a series of carboxylic acids has been elucidated for the
first time. The reactions proceed with release of hydrogen chloride and Cl/O interchange …

Energy dependence of H-exchange versus C C bond formation in the complex [CH3OH CH2 CH+ 2]: unimolecular and bimolecular studies

DJ McAdoo, MS Ahmed, CE Hudson… - International journal of …, 1990 - Elsevier
The reactions of the ion—neutral complex [CH3OH CH2 CH+ 2] have been examined by
unimolecular and bimolecular approaches. We conclude that the distonic ion CH3OH+ …

Mass spectra of alkenyl methyl ethers

RD Bowen, AD Wright, SR Thomas… - Organic mass …, 1991 - Wiley Online Library
Electron impact ionization mass spectra of numerous alkenyl methyl ethers CnH2n‐1OCH3
(n= 3–6) recorded under normal (4 kV, 70 eV, 175° C) and low‐energy, low‐temperature (8 …

Unimolecular reactions of the isolated immonium ions CH3CH = NH+C4H9, CH3CH2Ch = NH+C4H9 and (CH3)2C = NH+C4H9

RD Bowen, AW Colburn… - Organic mass …, 1990 - Wiley Online Library
The reactions of ten metastable immonium ions of general structure R1R2C NH+ C4H9
(R1= H, R2= CH3, C2H5; R1= R2= CH3) are reported and discussed. Elimination of C4H8 is …