We report the use of 1, 2, 3-triazole (Tz)-containing water microdroplets for gas-phase
carbon dioxide (CO2) reduction at room temperature. Using a coaxial sonic spraying setup …

Redox chemistry during the activation of carbon dioxide involves changing the charge state
in a CO2 molecular unit. However, such changes are usually not well described by integer …

Recent advances in the gas phase vibrational spectroscopy of mass-selected ions are
described, highlighting experiments on hydrogen-bonded (HBed) clusters relevant to …

Transforming the poisonous CO generated on the active metal sites promptly is essential for
Ni-based catalyst applying in aqueous-phase reforming (APR) of biomass-derived …

Proton transfer is crucial in various chemical and biological processes. Because of
significant nuclear quantum effects, accurate and efficient description of proton transfer …

Solvent effects are crucial for simulating chemical and biological processes in solutions. The
continuum solvation model is widely used for incorporating solvent effects with different …

Decarboxylation of carboxylate ions in the gas phase provides a useful window into the
chemistry displayed by these reactive carbanion intermediates. Here, we explore the …

We report the vibrational spectra of the hydronium and methyl-ammonium ions captured in
the C3 v binding pocket of the 18-crown-6 ether ionophore. Although the NH stretching …

Thermal excitation alters the spectroscopic signatures of solvated ions and affects their
interactions with neighboring molecules. By analyzing the photoelectron spectra of …

Nonadiabatic dynamical processes such as proton-coupled electron transfer and excited
state intramolecular proton transfer have been the subject of much research. One of the …