A survey of protein databases indicates that the majority of enzymes exist in oligomeric
forms, with about half of those found in the UniProt database being homodimeric …

Nitrene‐transfer reactions are powerful synthetic tools for the direct incorporation of nitrogen
atoms into organic molecules. The discovery of novel nitrene‐transfer reactions has been …

Nickel PyBox catalysts promote nucleophilic cyclopropanation reactions using CH2Cl2 as a
methylene source and Mn as a stoichiometric reductant. The substrate scope includes a …

Nickel complexes of a PCcarbeneP pincer ligand framework are described.
Dehydrobromination of the precursor (PCsp3P) NiBr in the presence of a donor (PPh3 or …

Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

This review article summarizes efforts to use nitrous oxide (N2O,'laughing gas') as a reagent
in synthetic chemistry. The focus will be on reactions which are carried out in homogeneous …

Since the seminal study by Curtius on the use of alkyl azides in organic chemistry,
particularly in CĀN bond-forming reactions, these readily available compounds have been …

A nickel‐catalyzed site‐selective intermolecular amidation of saturated C (sp3)− H bonds is
reported. This mild protocol exhibits a predictable reactivity pattern to incorporate amide …

Facile activation of nitrous oxide is achieved using a series of fluoroarylboranes, B (C6F5) 3,
PhB (C6F5) 2, MesB (C6F5) 2,(C6F5) 2BOC6F5, B (C6F4-pH) 3, B (C6H4-pF) 3 and 1, 4 …

A CuI catalyst (1), supported by a framework of strongly basic guanidinato moieties,
mediates nitrene-transfer from PhI NR sources to a wide variety of aliphatic hydrocarbons …