Quantum chemical investigations on molecular clusters

SR Gadre, SD Yeole, N Sahu - Chemical reviews, 2014 - ACS Publications
A cluster is an aggregate of bound atoms or molecules, intermediate in size between a
molecule and a bulk solid. Clusters of a variety of molecules are receiving increasing …

Comparative electron irradiations of amorphous and crystalline astrophysical ice analogues

DV Mifsud, PA Hailey, P Herczku, B Sulik… - Physical Chemistry …, 2022 - pubs.rsc.org
Laboratory studies of the radiation chemistry occurring in astrophysical ices have
demonstrated the dependence of this chemistry on a number of experimental parameters …

[HTML][HTML] Infrared spectra and band strengths of amorphous and crystalline N2O

RL Hudson, MJ Loeffler, PA Gerakines - The Journal of Chemical …, 2017 - pubs.aip.org
Infrared transmission spectra from 4000 to 400 cm− 1, and associated band strengths and
absorption coefficients, are presented for the first time for both amorphous and crystalline N …

Novel measurements of refractive index, density and mid-infrared integrated band strengths for solid O2, N2O and NO2: N2O4 mixtures

D Fulvio, B Sivaraman, GA Baratta, ME Palumbo… - … Acta Part A: Molecular …, 2009 - Elsevier
We present novel measurements of the refractive index, density and integrated band
strengths of mid-infrared features of solid N2O at 16K and of NO2 and N2O4 in two frozen …

No ice hydrogenation: a solid pathway to NH2OH formation in space

E Congiu, G Fedoseev, S Ioppolo… - The Astrophysical …, 2012 - iopscience.iop.org
Icy dust grains in space act as catalytic surfaces onto which complex molecules form. These
molecules are synthesized through exothermic reactions from precursor radicals and …

Efficient surface formation route of interstellar hydroxylamine through NO hydrogenation. I. The submonolayer regime on interstellar relevant substrates

E Congiu, H Chaabouni, C Laffon, P Parent… - The Journal of …, 2012 - pubs.aip.org
Dust grains in the interstellar medium are known to serve as the first chemical laboratory
where the rich inventory of interstellar molecules are synthesized. Here we present a study …

Simulated Interstellar Photolysis of N2O Ice: Selectivity in Photoproducts

BK Malla, S Chowdhury, D Paliwal, H KM… - The Journal of …, 2025 - ACS Publications
Thermal diffusion and recombination control the kinetics of photochemical reactions of
reactive radicals formed by ultraviolet photon irradiation in interstellar ices. Here, we show …

Processing of N2O ice by fast ions: implications on nitrogen chemistry in cold astrophysical environments

GC Almeida, S Pilling, ALF De Barros… - Monthly Notices of …, 2017 - academic.oup.com
Nitrous oxide, N2O, is found in the interstellar medium associated with dense molecular
clouds and its abundance is explained by active chemistry occurring on N2 rich ice surfaces …

Infrared Spectroscopic Study on Swift-Ion Irradiation of Solid N2O–H2O Samples: Synthesis of N–O Bearing Species in Astrophysical Ices

A Bergantini, ALF de Barros, NN Toribio… - The Journal of …, 2022 - ACS Publications
As of early 2022, only six species bearing an N–O bond have been detected toward cold
molecular clouds and regions of star formation. It is not clear yet if the small number of N–O …

Structural Elucidation of N2O Clusters at Low Temperatures: Exemplary Framework Stabilized by π-Hole-Driven N···O and N···N Pnicogen Bonding Interactions

N Mahapatra, S Chandra, N Ramanathan… - The Journal of …, 2024 - ACS Publications
N2O is a classic prototype, in which central nitrogen is sufficiently electropositive with a
positive potential of 20 kcal mol–1 in magnitude to qualify it as a possible pnicogen. This …