Reactions of hydrosilanes with transition metal complexes and characterization of the products

JY Corey - Chemical Reviews, 2011 - ACS Publications
Hydrosilanes are used as versatile coreactants in the generation of silyl-metal complexes.
Since organohydrosilanes may contain one, two, or three SiH bonds as tertiary, secondary …

Understanding the reactivity of transition metal complexes involving multiple spin states

JN Harvey, R Poli, KM Smith - Coordination chemistry reviews, 2003 - Elsevier
In coordination chemistry, many reactions involve several electronic states, in particular
states of different spin. This phenomenon of 'Multiple-State Reactivity'has been recognized …

Femtosecond quantum control of molecular dynamics in the condensed phase

P Nuernberger, G Vogt, T Brixner… - Physical Chemistry …, 2007 - pubs.rsc.org
We review the progress in controlling quantum dynamical processes in the condensed
phase with femtosecond laser pulses. Due to its high particle density the condensed phase …

Development of a broadband picosecond infrared spectrometer and its incorporation into an existing ultrafast time-resolved resonance Raman, UV/visible, and …

M Towrie, DC Grills, J Dyer, JA Weinstein… - Applied …, 2003 - opg.optica.org
We have constructed a broadband ultrafast time-resolved infrared (TRIR) spectrometer and
incorporated it into our existing time-resolved spectroscopy apparatus, thus creating a single …

A Combined Theoretical and Experimental Study on the Role of Spin States in the Chemistry of Fe(CO)5 Photoproducts

M Besora, JL Carreon-Macedo, AJ Cowan… - Journal of the …, 2009 - ACS Publications
A combined experimental and theoretical study is presented of several ligand addition
reactions of the triplet fragments 3Fe (CO) 4 and 3Fe (CO) 3 formed upon photolysis of Fe …

Ultrafast probes at the interfaces of solar energy conversion materials

X Chen, K Wang, MC Beard - Physical Chemistry Chemical Physics, 2019 - pubs.rsc.org
Ultrafast carrier dynamics at interfaces plays a major role in governing solar energy
conversion efficiency in solar conversion systems, especially in solar cells and …

Triplet organometallic reactivity under ambient conditions: an ultrafast UV pump/IR probe study

PT Snee, CK Payne, KT Kotz, H Yang… - Journal of the American …, 2001 - ACS Publications
The reactivity of triplet 16-electron organometallic species has been studied in room-
temperature solution using femtosecond UV pump IR probe spectroscopy. Specifically, the …

Ultrafast infrared studies of the role of spin states in organometallic reaction dynamics

JP Lomont, SC Nguyen, CB Harris - Accounts of Chemical …, 2014 - ACS Publications
Conspectus The importance of spin state changes in organometallic reactions is a topic of
significant interest, as an increasing number of reaction mechanisms involving changes of …

Mechanism for Iron-Catalyzed Alkene Isomerization in Solution

KR Sawyer, EA Glascoe, JF Cahoon… - …, 2008 - ACS Publications
Here we report nano-through microsecond time-resolved IR experiments of iron-catalyzed
alkene isomerization in room-temperature solution. We have monitored the photochemistry …

Using picosecond and nanosecond time-resolved infrared spectroscopy for the investigation of excited states and reaction intermediates of inorganic systems

MK Kuimova, WZ Alsindi, J Dyer, DC Grills… - Dalton …, 2003 - pubs.rsc.org
Time-resolved infrared (TRIR) spectroscopy, a combination of UV flash photolysis and fast
infrared detection, is a powerful technique for probing excited states and detecting reaction …