Hexaiododiplatinate (ii) as a useful supramolecular synthon for halogen bond involving crystal engineering

AA Eliseeva, DM Ivanov, AS Novikov, AV Rozhkov… - Dalton …, 2020 - pubs.rsc.org
Hexaiododiplatinates (II) bearing ammonium and phosphonium cations,[R4N] 2 [Pt2 (μ-I)
2I4]{R= Et (1) and n-Bu (2)} and [R3PR1] 2 [Pt2 (μ-I) 2I4]{R= n-Bu and R1= n-Bu (3); R= Ph …

Recognition of the π-hole donor ability of iodopentafluorobenzene–a conventional σ-hole donor for crystal engineering involving halogen bonding

AA Eliseeva, DM Ivanov, AS Novikov, VY Kukushkin - CrystEngComm, 2019 - pubs.rsc.org
Iodopentafluorobenzene (IPFB or PhFI) was co-crystallized with tetra (n-butyl) ammonium
tetraiodo-μ, μ′-diiododiplatinate (II),[n-Bu4N] 2 [Pt2 (μ-I2) I4](1), to give the adduct 1· 2IPFB …

Exploring the structure–property schemes in anion–π systems of d-block metalates

E Kuzniak-Glanowska, J Kobylarczyk… - Dalton …, 2021 - pubs.rsc.org
Anion–π based compounds, materials, and processes have gained significant interest due
to the diversity of their aesthetic non-covalent synthons, and thanks to their significance in …

Fabrication of a novel chitosan/polyaspartic acid composite: A pH-tunable sorbent for efficient adsorption of heavy metal ions and dyes from water

W Jiang, Y Yang, S Miao, D Wan - Journal of Water Process Engineering, 2023 - Elsevier
Heavy metal ions and dyes pollutants have caused significant environmental pollution,
posing a threat to human life and ecosystems. Herein, a novel pH-tunable composite …

Exploring the Nature of Anion− π Interactions: Complexes of π-Acceptors with Fluoro-or Oxoanions Compared to the Associations with Halides

FE Odubo, M Zeller, SV Rosokha - The Journal of Physical …, 2023 - ACS Publications
The variations in the nature and properties of the anion− π complexes with different types of
anions are identified via experimental (UV–vis and X-ray crystallographic) measurements …

Diversity and uniformity in anion–π complexes of thiocyanate with aromatic, olefinic and quinoidal π-acceptors

J Wilson, T Maxson, I Wright, M Zeller… - Dalton Transactions, 2020 - pubs.rsc.org
Despite the progress in the study of anion–π interactions, there are still inconsistencies in
the use of this term and the experimental data about factors affecting the strength of such …

Rotating Magnetocaloric Effect in an Anisotropic Two-Dimensional CuII[WV(CN)8]3– Molecular Magnet with Topological Phase Transition: Experiment and Theory

P Konieczny, R Pełka, D Czernia… - Inorganic Chemistry, 2017 - ACS Publications
Conventional (MCE) and rotating (RMCE) magnetocaloric effects have been explored in the
two-dimensional (2D) coordination polymer {(tetren) H5) 0.8 CuII4 [WV (CN) 8] 4· 7.2 H2O} n …

Structural preferences in strong anion–π and halogen-bonded complexes: π-and σ-holes vs. frontier orbitals interaction

O Grounds, M Zeller, SV Rosokha - New Journal of Chemistry, 2018 - pubs.rsc.org
X-ray crystallographic and computational analyses of supramolecular associates between
the tetracyanopyrazine π-acceptor and halide anions, as well as between brominated …

Influence of O‐H··· Pt interactions on photoluminescent response in the (Bu4N) 2 {[Pt (bph)(CN) 2][phenylene‐1, 4‐diresorcinol]} framework

D Glosz, K Jędrzejowska, G Niedzielski… - … A European Journal, 2024 - Wiley Online Library
Tunable photoluminescence (PL) is one of the hot topics in current materials science, and
research performed on the molecular phases is at the forefront of this field. We present the …

Binding of anionic Pt (II) complexes in a dedicated organic matrix: towards new binary crystalline composites

E Kuzniak-Glanowska, D Glosz, G Niedzielski… - Dalton …, 2021 - pubs.rsc.org
The square-planar [PtX4] 2− complexes (X= Cl, Br) were successfully incorporated into
preprogrammed hybrid organic–inorganic systems, exploiting their expected strong anion–π …