A field guide to flow chemistry for synthetic organic chemists

L Capaldo, Z Wen, T Noël - Chemical science, 2023 - pubs.rsc.org
Flow chemistry has unlocked a world of possibilities for the synthetic community, but the idea
that it is a mysterious “black box” needs to go. In this review, we show that several of the …

Electrochemical synthesis of high-nitrogen materials and energetic materials

J Yount, DG Piercey - Chemical reviews, 2022 - ACS Publications
Electrochemical synthesis is a valuable method for the preparation of molecules. It is
innately eco-friendly, as potentially hazardous oxidation and reduction agents are replaced …

Advanced energetic materials: novel strategies and versatile applications

SG Zlotin, AM Churakov, MP Egorov, LL Fershtat… - Mendeleev …, 2021 - Elsevier
Novel efficient synthetic strategies, including green methodologies, to basic and perspective
high-energy density compounds, bearing active oxygen sources (C-, N-and O-nitro groups …

Understanding the structure–polymerization thermodynamics relationships of fused-ring cyclooctenes for developing chemically recyclable polymers

J Zhou, D Sathe, J Wang - Journal of the American Chemical …, 2022 - ACS Publications
Polymers that can be chemically recycled to their constituent monomers offer a promising
solution to address the challenges in plastics sustainability through a circular use of …

Stereochemical editing logic powered by the epimerization of unactivated tertiary stereocenters

YA Zhang, V Palani, AE Seim, Y Wang, KJ Wang… - Science, 2022 - science.org
The stereoselective synthesis of complex targets requires the precise orchestration of
chemical transformations that simultaneously establish the connectivity and spatial …

Size-matched hydrogen bonded hydroxylammonium frameworks for regulation of energetic materials

Q Lai, L Pei, T Fei, P Yin, S Pang, JM Shreeve - Nature communications, 2022 - nature.com
Size matching molecular design utilizing host-guest chemistry is a general, promising
strategy for seeking new functional materials. With the growing trend of multidisciplinary …

1, 2, 5‐Oxadiazole‐Based High‐Energy‐Density Materials: Synthesis and Performance

LL Fershtat, NN Makhova - ChemPlusChem, 2020 - Wiley Online Library
This Review covers the synthesis and performance of the most promising 1, 2, 5‐oxadiazole‐
based high‐energy density materials (HEDMs). These materials comprise a 1, 2, 5 …

Toward advanced high-performance insensitive FOX-7-like energetic materials via positional isomerization

Z Yin, W Huang, Z Zeng, Y Liu… - ACS Applied Materials …, 2022 - ACS Publications
For an energetic molecule with a definite elemental composition, the substituent type and
position are the most important factors to influence its detonation performance and …

A short review of nitric esters and their role in energetic materials

JJ Sabatini, EC Johnson - ACS omega, 2021 - ACS Publications
A review of energetic materials based on the nitric ester functionality is presented. Examined
are materials that are classified as primary explosives, pressable secondary explosives, melt …

Learning to fly: thermochemistry of energetic materials by modified thermogravimetric analysis and highly accurate quantum chemical calculations

NV Muravyev, KA Monogarov, IN Melnikov… - Physical Chemistry …, 2021 - pubs.rsc.org
The standard state enthalpy of formation and the enthalpy of sublimation are essential
thermochemical parameters determining the performance and application prospects of …