Recent Advances in the Construction of Phosphorus‐Substituted Heterocycles, 2009–2019

L Chen, XY Liu, YX Zou - Advanced Synthesis & Catalysis, 2020 - Wiley Online Library
Phosphorus‐substituted heterocycles represent an important class of organophosphorus
compounds, which not only widely exist in biologically active pharmaceuticals …

Recent advances in pyrazole synthesis employing diazo compounds and synthetic analogues

SP Chandrasekharan, A Dhami, S Kumar… - Organic & Biomolecular …, 2022 - pubs.rsc.org
Pyrazole is an essential structural component of many pharmaceuticals and agrochemicals.
The synthesis of pyrazoles has been a subject of intense research for several decades …

λ5-Phosphorus-Containing α-Diazo Compounds: A Valuable Tool for Accessing Phosphorus-Functionalized Molecules

M Marinozzi, F Pertusati, M Serpi - Chemical Reviews, 2016 - ACS Publications
The compounds characterized by the presence of a λ5-phosphorus functionality at the α-
position with respect to the diazo moiety, here referred to as λ5-phosphorus-containing α …

Synthesis of spirobidihydropyrazole through double 1, 3-dipolar cycloaddition of nitrilimines with allenoates

H Liu, H Jia, B Wang, Y Xiao, H Guo - Organic letters, 2017 - ACS Publications
The double 1, 3-dipolar cycloaddition of allenoates with nitrilimines has been achieved
under mild reaction conditions, affording a variety of spirobidihydropyrazoles in moderate to …

Organocatalytic enantioselective 1, 3-dipolar cycloadditions between Seyferth–Gilbert reagent and isatylidene malononitriles: synthesis of chiral spiro …

T Du, F Du, Y Ning, Y Peng - Organic letters, 2015 - ACS Publications
A new method has been developed for the catalytic enantioselective 1, 3-dipolar
cycloaddition of the Seyferth–Gilbert reagent (SGR) to isatylidene malononitriles using a …

In situ generation of quinolinium ylides from diazo compounds: copper-catalyzed synthesis of indolizine

R Chen, Y Zhao, H Sun, Y Shao, Y Xu… - The Journal of …, 2017 - ACS Publications
The Cu-catalyzed three-component reaction between quinolines, diazo compounds, and
alkenes has been established for direct construction of indolizine derivatives via quinolinium …

Bestmann–Ohira Reagent: A Convenient and Promising Reagent in the Chemical World

M Dhameja, J Pandey - Asian Journal of Organic Chemistry, 2018 - Wiley Online Library
Abstract The Bestmann–Ohira reagent is a unique and versatile reagent in organic
synthesis. It is a well‐known homologating agent for the conversion of aldehydes into the …

Switchable Synthesis of 3-Substituted 1H-Indazoles and 3,3-Disubstituted 3H-Indazole-3-phosphonates Tuned by Phosphoryl Groups

G Chen, M Hu, Y Peng - The Journal of Organic Chemistry, 2018 - ACS Publications
3-Alkyl/aryl-1 H-indazoles and 3-alkyl/aryl-3 H-indazole-3-phosphonates were synthesized
efficiently through a 1, 3-dipolar cycloaddition reaction between α-substituted α …

Cyclocondensation of arylhydrazines with 1, 3-bis (het) arylmonothio-1, 3-diketones and 1, 3-bis (het) aryl-3-(methylthio)-2-propenones: Synthesis of 1-aryl-3, 5-bis …

SV Kumar, SK Yadav, B Raghava… - The Journal of …, 2013 - ACS Publications
Two efficient highly regioselective routes for the synthesis of unsymmetrically substituted 1-
aryl-3, 5-bis (het) arylpyrazoles with complementary regioselectivity starting from active …

Metal-free three-component domino approach to phosphonylated triazolines and triazoles

S Ahamad, R Kant, K Mohanan - Organic letters, 2016 - ACS Publications
An efficient, three-component domino reaction between aldehydes, amines, and the
Bestmann–Ohira reagent is reported that enables a general, mild, and straightforward …