Lipid peroxidation produces a diverse mixture of saturated and unsaturated aldehydes in exhaled breath that can serve as biomarkers of lung cancer—a review

SR Sutaria, SS Gori, JD Morris, Z Xie, XA Fu, MH Nantz - Metabolites, 2022 - mdpi.com
The peroxidation of unsaturated fatty acids is a widely recognized metabolic process that
creates a complex mixture of volatile organic compounds including aldehydes. Elevated …

To DISP or Not? The Far‐Reaching Reaction Mechanisms Underpinning Lithium‐Air Batteries

RB Jethwa, S Mondal, B Pant… - Angewandte Chemie …, 2024 - Wiley Online Library
The short history of research on Li− O2 batteries has seen a remarkable number of
mechanistic U‐turns over the years. From the initial use of carbonate electrolytes, that were …

Criegee intermediates beyond ozonolysis: Synthetic and mechanistic insights

Z Hassan, M Stahlberger… - Angewandte Chemie …, 2021 - Wiley Online Library
After more than 70 years since their discovery, Criegee intermediates (CIs) are back at the
forefront of modern chemistry of short‐lived reactive intermediates. They play an important …

Alkene ozonolysis

TJ Fisher, PH Dussault - Tetrahedron, 2017 - Elsevier
Alkene ozonolysis - ScienceDirect Skip to main contentSkip to article Elsevier logo Journals &
Books Search RegisterSign in View PDF Download full issue View Open Manuscript Other …

Singlet oxygen-mediated selective C–H bond hydroperoxidation of ethereal hydrocarbons

A Sagadevan, KC Hwang, MD Su - Nature Communications, 2017 - nature.com
Singlet O2 is a key reactive oxygen species responsible for photodynamic therapy and is
generally recognized to be chemically reactive towards C= C double bonds. Herein, we …

Effects of acidity on reactive oxygen species formation from secondary organic aerosols

J Wei, T Fang, M Shiraiwa - ACS environmental Au, 2022 - ACS Publications
Reactive oxygen species (ROS) play a critical role in the chemical transformation of
atmospheric secondary organic aerosols (SOA) and aerosol health effects by causing …

Alternative method to Baeyer–Villiger oxidation of cyclobutenones using I 2/DMSO catalytic systems

Y Sun, Z Hu, J Peng, Q Qin, N Jiao - Green Chemistry, 2023 - pubs.rsc.org
The Baeyer–Villiger oxidation represents a valuable reaction that enables the conversion of
ketones into esters or lactones. Here, we present a novel and efficient approach utilizing I2 …

Inverse α-Effect as the Ariadne's Thread on the Way to Tricyclic Aminoperoxides: Avoiding Thermodynamic Traps in the Labyrinth of Possibilities

IA Yaremenko, YY Belyakova, PS Radulov… - Journal of the …, 2022 - ACS Publications
Stable tricyclic aminoperoxides can be selectively assembled via a catalyst-free three-
component condensation of β, δ′-triketones, H2O2, and an NH-group source such as …

Novofumigatonin biosynthesis involves a non-heme iron-dependent endoperoxide isomerase for orthoester formation

Y Matsuda, T Bai, CBW Phippen, CS Nødvig… - Nature …, 2018 - nature.com
Abstract Novofumigatonin (1), isolated from the fungus Aspergillus novofumigatus, is a
heavily oxygenated meroterpenoid containing a unique orthoester moiety. Despite the wide …

Oxidation and degradation of (epi) gallocatechin gallate (EGCG/GCG) and (epi) catechin gallate (ECG/CG) in alkali solution

H Peng, F Shahidi - Food Chemistry, 2023 - Elsevier
The oxidative decomposition/degradation of two main tea flavanols, EGCG/GCG and
ECG/CG, was studied in alkaline solution under ultrasonic-assisted thermal conditions. The …