Implanted muon studies in condensed matter science

SFJ Cox - Journal of Physics C: Solid State Physics, 1987 - iopscience.iop.org
The positive muon is a unique microscopic probe. When it is implanted in condensed matter,
the evolution of its spin polarisation may be readily monitored to give information on the …

Muonium as a model for interstitial hydrogen in the semiconducting and semimetallic elements

SFJ Cox - Reports on Progress in Physics, 2009 - iopscience.iop.org
Although the interstitial hydrogen atom would seem to be one of the simplest defect centres
in any lattice, its solid state chemistry is in fact unknown in many materials, not least amongst …

The positive muon and μSR spectroscopy: powerful tools for investigating the structure and dynamics of free radicals and spin probes in complex systems

I McKenzie - Annual Reports Section" C"(Physical Chemistry), 2013 - pubs.rsc.org
The positive muon (μ+) can be incorporated into free radicals where it acts as a probe of the
structure and dynamics. The muoniated radicals are characterized by a series of magnetic …

Probing Radical Addition to 1‐Phosphabutadienes by Employing Muonium as a “Light Isotope” of Hydrogen

HTG Walsgrove, PW Percival… - Chemistry–A European …, 2024 - Wiley Online Library
Understanding free radical addition to multiple bonds is important to elucidating the
mechanistic details of addition polymerization reactions, albeit the fleeting radical …

Kinetic isotope effects in solution reactions of muonium atoms as H-isotopes

DC Walker - Journal of the Chemical Society, Faraday Transactions, 1998 - pubs.rsc.org
Muonium (Mu) and protium (1H) differ by only 0.43% in reduced mass but by a factor of 8.8
in atomic mass, so they constitute an excellent pair of atoms with which to examine kinetic …

Hyperfine coupling constants in muonium adducts of the carbonyl bond

SFJ Cox, DA Geeson, CJ Rhodes, E Roduner… - Hyperfine …, 1986 - Springer
A representative series is studies of organic radicals formed by the effective addition of
muonium to the carbonyl oxygen atom of aldehydes, ketones, esters and amides. Low …

Enolization of acetone in superheated water detected via radical formation

K Ghandi, B Addison-Jones… - Journal of the …, 2003 - ACS Publications
Muoniated free radicals have been detected in muon-irradiated aqueous solutions of
acetone at high temperatures and pressures. At temperatures below 250° C, the radical …

Solvent effects on the hyperfine coupling constant and barrier to internal rotation for the 2-muoxyprop-2-Yl radical

D Buttar, RM Macrae, BC Webster, E Roduner - Hyperfine Interactions, 1991 - Springer
The muon-electron β-hyperfine coupling constant is reported for the 2-muoxyprop-2-yl
radical formed by positive muon (μ+) implantation in propan-2-one and aqueous solutions of …

Organic free radicals in superheated water studied by muon spin spectroscopy

PW Percival, JC Brodovitch, K Ghandi… - Journal of the …, 2005 - ACS Publications
There is a pressing need to identify and monitor reaction intermediates in water at high
temperatures and pressures, but conventional techniques have limited capability for …

Density functional studies of hydrogen atom addition to the CS bond

RM Macrae, I Carmichael - The Journal of Physical Chemistry A, 2001 - ACS Publications
The results of density functional theory calculations on the structures, energetics, and
hyperfine properties of radical H adducts to the C and S atoms of several thioketones and …