Atomically precise alloy nanoclusters: syntheses, structures, and properties

X Kang, Y Li, M Zhu, R Jin - Chemical Society Reviews, 2020 - pubs.rsc.org
Metal nanoclusters fill the gap between discrete atoms and plasmonic nanoparticles,
providing unique opportunities for investigating the quantum effects and precise structure …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …

Chiral Hydride Cu18 Clusters Transform to Superatomic Cu15Ag4 Clusters: Circularly Polarized Luminescence Lighting

MM Zhang, KK Gao, XY Dong, Y Si, T Jia… - Journal of the …, 2023 - ACS Publications
The manipulation of metal cluster enantiomers and their reconstruction remain challenging.
Here, for the first time, we report an enantiomeric pair of hydride copper clusters [Cu18H …

Alloy clusters: Precise synthesis and mixing effects

S Hossain, Y Niihori, LV Nair, B Kumar… - Accounts of Chemical …, 2018 - ACS Publications
Conspectus Metal alloys exhibit functionalities unlike those of single metals. Such alloying
has drawn considerable research interest, particularly for nanoscale particles (metal …

Au 25 (SR) 18: the captain of the great nanocluster ship

X Kang, H Chong, M Zhu - Nanoscale, 2018 - pubs.rsc.org
Noble metal nanoclusters are in the intermediate state between discrete atoms and
plasmonic nanoparticles and are of significance due to their atomically accurate structures …

Sub-nanometre sized metal clusters: from synthetic challenges to the unique property discoveries

Y Lu, W Chen - Chemical Society Reviews, 2012 - pubs.rsc.org
Sub-nanometre sized metal clusters, with dimensions between metal atoms and
nanoparticles, have attracted more and more attention due to their unique electronic …

Quantum sized gold nanoclusters with atomic precision

H Qian, M Zhu, Z Wu, R Jin - Accounts of chemical research, 2012 - ACS Publications
Gold nanoparticles typically have a metallic core, and the electronic conduction band
consists of quasicontinuous energy levels (ie spacing δ≪ k BT, where k BT is the thermal …

Self-assembled monolayers of thiols and dithiols on gold: new challenges for a well-known system

C Vericat, ME Vela, G Benitez, P Carro… - Chemical Society …, 2010 - pubs.rsc.org
Self-assembled monolayers (SAMs) of alkanethiols and dialkanethiols on gold are key
elements for building many systems and devices with applications in the wide field of …

Quantum sized, thiolate-protected gold nanoclusters

R Jin - Nanoscale, 2010 - pubs.rsc.org
The scientific study of gold nanoparticles (typically 1–100 nm) has spanned more than 150
years since Faraday's time and will apparently last longer. This review will focus on a special …