Nickel binding enables isolation and reactivity of previously inaccessible 7-aza-2, 3-indolynes
JN Humke, RG Belli, EE Plasek, SS Kargbo, AQ Ansel… - Science, 2024 - science.org
N-Heteroaromatics are key elements of pharmaceuticals, agrochemicals, and materials. N-
Heteroarynes provide a scaffold to build these essential molecules but are underused …
Heteroarynes provide a scaffold to build these essential molecules but are underused …
Dual-Ligand Strategy for the Preparation of Gas-Phase Uranyl (VI) Benzyne Complexes from Uranyl (VI) Benzoates
Z Xiong, M Yang, X Chen, Y Gong - Inorganic Chemistry, 2023 - ACS Publications
The uranyl (VI) benzyne complex (η2-C6H4) UO2Cl–was prepared in the gas phase by
electrospray ionization mass spectrometry coupled with collision-induced dissociation. It …
electrospray ionization mass spectrometry coupled with collision-induced dissociation. It …
Zirconium-Mediated Carbon-Fluorine Bond Functionalisation Through Cyclohexyne “Umpolung”
Polarity reversal, or “umpolung”, is a widely acknowledged strategy to allow organic
functional groups amenable to react in alternative ways to the usual preference set by their …
functional groups amenable to react in alternative ways to the usual preference set by their …
Gas-phase synthesis and structure of thorium benzyne complexes
X Chen, Z Xiong, M Yang, Y Gong - Chemical Communications, 2022 - pubs.rsc.org
The thorium benzyne complex (η2-C6H4) ThCl3− was synthesized in the gas phase through
consecutive decarboxylation and dehydrochlorination from the (C6H5CO2) ThCl4 …
consecutive decarboxylation and dehydrochlorination from the (C6H5CO2) ThCl4 …
Nickel-Carbon σ-Bonded Complexes
CL Wagner, T Diao - … Organometallic Chemistry IV: Volume 1 …, 2022 - nyuscholars.nyu.edu
This chapter documents nickel aryl and alkyl complexes. The complexes are organized by
their supporting ligands such as tridentate, bidentate and monodentate ligands. Pincer …
their supporting ligands such as tridentate, bidentate and monodentate ligands. Pincer …
Spontaneous Combustion of 2-Bromo-3-Methoxythiophene: A Study on Reaction Pathways and Energetics by Quantum Chemical Calculations
S Okude, K Koizumi, Y Sakamoto… - The Journal of …, 2021 - ACS Publications
Reaction pathways and energetics for the dimerization and trimerization reactions of 2-
bromo-3-methoxythiophene (2Br-3Met) molecules are investigated using hybrid density …
bromo-3-methoxythiophene (2Br-3Met) molecules are investigated using hybrid density …