Ligands for f-element extraction used in the nuclear fuel cycle

A Leoncini, J Huskens, W Verboom - Chemical Society Reviews, 2017 - pubs.rsc.org
Liquid–liquid extraction is the major technique being applied for the partitioning of f-
elements from nuclear waste. In this review, the recent developments in ligand design …

Separation of actinides from spent nuclear fuel: A review

J Veliscek-Carolan - Journal of hazardous materials, 2016 - Elsevier
This review summarises the methods currently available to extract radioactive actinide
elements from solutions of spent nuclear fuel. This separation of actinides reduces the …

Separation of trivalent actinides and lanthanides using various 'N','S'and mixed 'N, O'donor ligands: a review

A Bhattacharyya, PK Mohapatra - Radiochimica Acta, 2019 - degruyter.com
Separation of trivalent actinide (An) and lanthanide (Ln) elements is one of the burning
topics in the back end of the nuclear fuel cycle due to the similarity in their chemical …

Actinide Lanthanide Separation Process ALSEP

AV Gelis, GJ Lumetta - Industrial & Engineering Chemistry …, 2014 - ACS Publications
Separation of the minor actinides (Am, Cm) from the lanthanides at an industrial scale
remains a significant technical challenge for closing the nuclear fuel cycle. To increase the …

An overview of solvent extraction processes developed in Europe for advanced nuclear fuel recycling, part 1—Heterogeneous recycling

A Geist, JM Adnet, S Bourg, C Ekberg… - Separation science …, 2021 - Taylor & Francis
The hydrometallurgical separation concepts for the heterogeneous recycling of irradiated
nuclear fuel developed in Europe are presented and discussed. Most of these concepts …

Recovery of minor actinides from high-level wastes: modern trends

MY Alyapyshev, VA Babain… - Russian Chemical …, 2016 - iopscience.iop.org
One of the major problems of nuclear power industry is associated with large amounts of
radioactive wastes. Contemporary reprocessing technologies of spent nuclear fuel generate …

The actinide-lanthanide separation concept

GJ Lumetta, AV Gelis, JC Carter, CM Niver… - … Extraction and Ion …, 2014 - Taylor & Francis
The Actinide-Lanthanide SEParation (ALSEP) concept is described. This concept is based
on using an extractant phase consisting of either N, N, N', N'-tetraoctyldiglycolamide …

Isolation and Purification of Actinides Using N, O-Hybrid Donor Ligands for Closing the Nuclear Fuel Cycle

M Alyapyshev, V Babain, D Kirsanov - Energies, 2022 - mdpi.com
Despite the fact that in the mass consciousness nuclear power is associated with increased
environmental risks, this type of energy today remains one of the cleanest, most efficient and …

Time-resolved laser fluorescence spectroscopy study of the coordination chemistry of a hydrophilic CHON [1, 2, 3-triazol-4-yl] pyridine ligand with Cm (III) and Eu (III)

C Wagner, E Mossini, E Macerata, M Mariani… - Inorganic …, 2017 - ACS Publications
The complexation of Cm (III) and Eu (III) with the novel i-SANEX complexing agent 2, 6-bis [1-
(propan-1-ol)-1, 2, 3-triazol-4-yl] pyridine (PTD) was studied by time-resolved laser …

An experimental and computational look at the radiolytic degradation of TODGA and the effect on metal complexation

A Kimberlin, D Guillaumont, S Arpigny… - New Journal of …, 2021 - pubs.rsc.org
Diglycolamide extractants, and in particular N, N, N′, N′-tetraoctyl diglycolamide
(TODGA), are currently under investigation for use in nuclear fuel reprocessing by liquid …