Heterogenisation of polyoxometalates and other metal-based complexes in metal–organic frameworks: from synthesis to characterisation and applications in catalysis

P Mialane, C Mellot-Draznieks, P Gairola… - Chemical Society …, 2021 - pubs.rsc.org
The last few years have seen huge growing interest in the heterogenisation of molecular
catalysts since it allows combining the advantages of homogeneous and heterogeneous …

Electrochemical oxidation of organic molecules at lower overpotential: Accessing broader functional group compatibility with electron− proton transfer mediators

F Wang, SS Stahl - Accounts of chemical research, 2020 - ACS Publications
Conspectus Electrochemical organic oxidation reactions are highly appealing because
protons are often effective terminal electron acceptors, thereby avoiding undesirable …

Carbon-based single-atom catalysts for advanced applications

MB Gawande, P Fornasiero, R Zbořil - Acs Catalysis, 2020 - ACS Publications
Carbon-based materials are widely employed as metal-free catalysts or supports in
catalysis, energy, and ecological applications because of their interesting properties …

Gram‐scale synthesis of high‐loading single‐atomic‐site Fe catalysts for effective epoxidation of styrene

Y Xiong, W Sun, P Xin, W Chen, X Zheng… - Advanced …, 2020 - Wiley Online Library
Abstract Single‐atomic‐site (SAS) catalysts, a new frontier of catalysts, always show
extremely high atom efficiency and unexpected catalytic properties. Herein, a pyrolyzing …

Molecular oxygen-mediated oxygenation reactions involving radicals

C Tang, X Qiu, Z Cheng, N Jiao - Chemical Society Reviews, 2021 - pubs.rsc.org
Molecular oxygen as a green, non-toxic and inexpensive oxidant has displayed lots of
advantages compared with other oxidants towards more selective, sustainable, and …

Artificial metalloenzymes: reaction scope and optimization strategies

F Schwizer, Y Okamoto, T Heinisch, Y Gu… - Chemical …, 2018 - ACS Publications
The incorporation of a synthetic, catalytically competent metallocofactor into a protein
scaffold to generate an artificial metalloenzyme (ArM) has been explored since the late …

Oxygenation via C–H/C–C bond activation with molecular oxygen

YF Liang, N Jiao - Accounts of Chemical Research, 2017 - ACS Publications
Conspectus The selective oxidation of organic molecules is a fundamentally important
component of modern synthetic chemistry. In the past decades, direct oxidative C–H and C …

Catalytic Asymmetric Oxygenations with the Environmentally Benign Oxidants H2O2 and O2

KP Bryliakov - Chemical reviews, 2017 - ACS Publications
The discovery of simple and efficient catalyst systems for the asymmetric
oxofunctionalization of hydrocarbons is a challenging task of catalytic chemistry. In this …

Combinations of aminocatalysts and metal catalysts: a powerful cooperative approach in selective organic synthesis

S Afewerki, A Cordova - Chemical reviews, 2016 - ACS Publications
The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

Rational design of bioinspired catalysts for selective oxidations

L Vicens, G Olivo, M Costas - ACS Catalysis, 2020 - ACS Publications
Recognizing Nature's unique ability to perform challenging oxygenation reactions with
exquisite selectivity parameters at iron-dependent oxygenases, chemists have long sought …