Synthesis and applications of carbohydrate-based organocatalysts

E Wojaczyńska, F Steppeler, D Iwan, MC Scherrmann… - Molecules, 2021 - mdpi.com
Organocatalysis is a very useful tool for the asymmetric synthesis of biologically or
pharmacologically active compounds because it avoids the use of noxious metals, which are …

Recent advances in carbohydrate polymers as a catalyst for organic synthesis: An update

A Taoufyk, K Oudghiri, M Taourirte… - Synthetic …, 2024 - Taylor & Francis
The biocompatibility, specificity, and consistency of natural carbohydrate polymers in
catalyzing organic processes have garnered significant interest. For the production of …

Supported Bifunctional Chiral Thioureas as Catalysts in the Synthesis of 3‐Amino‐2‐Oxindoles through Enantioselective aza‐Friedel‐Crafts Reaction: Application in …

M Rodríguez‐Rodríguez, A Maestro… - Advanced Synthesis …, 2020 - Wiley Online Library
Supported cinchone‐derived thioureas promote highly enantioselective aza‐Friedel‐Crafts
reaction of different naphthols with a variety of N‐Boc ketimines derived from isatin. The …

Chiral Bifunctional Thioureas and Squaramides and Their Copolymers as Recoverable Organocatalysts. Stereoselective Synthesis of 2-Substituted 4-Amino-3 …

JM Andrés, A Maestro, M Valle… - The Journal of organic …, 2018 - ACS Publications
Novel styryl-substituted thioureas and squaramides were obtained in three steps from
commercially available 4-hydroxy-3, 5-dichloroaniline. These organocatalysts promote …

Thioureas and their cyclized derivatives: Synthesis, conformational analysis and antimicrobial evaluation

ST Tuncel, SE Gunal, M Ekizoglu, NG Kelekci… - Journal of Molecular …, 2019 - Elsevier
Several single enantiomer thioureas have been synthesized and have been converted to
their cyclic derivatives: 2-imino-thiazolidin-4-ones. The conformations of the thioureas have …

Chitosan-supported cinchona urea: Sustainable organocatalyst for asymmetric Michael reaction

MA Abdelkawy, ESA Aly, MA El-Badawi… - Catalysis Communications, 2020 - Elsevier
A novel chitosan-supported cinchona urea heterogeneous catalyst was developed for
asymmetric reaction. The catalytic activity of the chitosan-supported organocatalyst was …

Recoverable PEG-supported amino alcohol ligand for copper-catalyzed Enantio-and syn-selective henry reaction with nitroethanol: Sustainable and straightforward …

Y Xia, Y Ning, M Liu, FE Chen - Journal of Catalysis, 2023 - Elsevier
A poly (ethylene glycol)(PEG) supported amino alcohol has been developed as a chiral
ligand to promote the copper-catalyzed asymmetric nitrolaldol reaction (Henry Reaction) …

Synthesis of Enantioenriched 3‐Amino‐3‐Substituted Oxindoles by Stereoselective Mannich Reaction Catalyzed by Supported Bifunctional Thioureas.

P Rodríguez‐Ferrer, M Sanz‐Novo… - Advanced Synthesis …, 2019 - Wiley Online Library
Abstract Enantioenriched 3‐amino‐3‐substituted oxindoles have been obtained by addition
of different nucleophiles to N‐Boc ketimines derived from isatin catalyzed by chiral …

Novel Chiral Thiourea Derived from Hydroquinine and l-Phenylglycinol: An Effective Catalyst for Enantio- and Diastereoselective Aza-Henry Reaction

J Wang, Y Liu, Z Wei, J Cao, D Liang, Y Lin, H Duan - ACS omega, 2021 - ACS Publications
A series of chiral thiourea bearing multiple H-bond donors derived from hydroquinine has
been reported. The aza-Henry reaction of isatin-derived ketimines and long-chain …

Mesoporous chitosan‐immobilized iron tetrakis (4‐carboxyphenyl) porphyrin as a model of cytochrome P‐450 enzyme for oxidation of ethylbenzene

G Huang, T Su, K Zeng, Y Guo… - Applied Organometallic …, 2018 - Wiley Online Library
Mesoporous chitosan‐grafted iron tetra (4‐carboxyphenyl) porphyrin catalyst (Fe
TCPP/mesp‐CTS) was prepared and investigated as a practical model for the nano‐cavity …