Transmetalation of unsaturated carbon nucleophiles from boron-containing species to the mid to late d-block metals of relevance to catalytic C− X coupling reactions …

DV Partyka - Chemical Reviews, 2011 - ACS Publications
Though often perceived as the simple metaphorical hybrid of synthetic inorganic and
organic chemistry, synthetic organometallic chemistry continues to vigorously differentiate …

Formation, reactivity, and properties of nondative late transition metal− oxygen and− nitrogen bonds

JR Fulton, AW Holland, DJ Fox… - Accounts of chemical …, 2002 - ACS Publications
Complexes containing bonds between heteroatoms such as nitrogen and oxygen and “late”
transition metals (ie, those located on the right side of the transition series) have been …

Transesterification

J Otera - Chemical reviews, 1993 - ACS Publications
Transesterification is one of the classic organic reactions that have enjoyed numerous
laboratory uses and industrial applications. Organic chemists make use of this reaction quite …

The metal− ligand bifunctional catalysis: A theoretical study on the ruthenium (II)-catalyzed hydrogen transfer between alcohols and carbonyl compounds

M Yamakawa, H Ito, R Noyori - Journal of the American Chemical …, 2000 - ACS Publications
The ternary system consisting of [RuCl2 (η6-benzene)] 2, N-tosylethylenediamine or
ethanolamine, and KOH (Ru: amine: KOH= 1: 1: 2 molar ratio) catalyzes reversible hydrogen …

Organolanthanide-catalyzed hydroamination. A kinetic, mechanistic, and diastereoselectivity study of the cyclization of N-unprotected amino olefins

MR Gagne, CL Stern, TJ Marks - Journal of the American …, 1992 - ACS Publications
CH3, CH2CH3; Ln= Nd, R= CH2CH3) and Cp'2LaŅCH (CH3) CH2CR2CH2 (HNCH (CH3)
CH2CR2CH2)(R= H, CH3) were synthesized to model species in the catalytic cycle …

Hydrogen Bonding in Organometallic Crystals. 6. X− H---M Hydrogen Bonds and M---(H− X) Pseudo-Agostic Bonds

D Braga, F Grepioni, E Tedesco, K Biradha… - …, 1997 - ACS Publications
The intermolecular interactions between X− H groups (X= C, N, and O) and metal atoms in
crystalline organometallic complexes have been investigated. Molecular and crystal …

Room-Temperature Direct β-Arylation of Thiophenes and Benzo[b]thiophenes and Kinetic Evidence for a Heck-type Pathway

C Colletto, S Islam, F Julia-Hernandez… - Journal of the American …, 2016 - ACS Publications
The first example of a regioselective β-arylation of benzo [b] thiophenes and thiophenes at
room temperature with aryl iodides as coupling partners is reported. This methodology …

Ruthenium(II) Terdentate CNN Complexes: Superlative Catalysts for the Hydrogen‐Transfer Reduction of Ketones by Reversible Insertion of a Carbonyl Group into …

W Baratta, G Chelucci, S Gladiali… - Angewandte Chemie …, 2005 - Wiley Online Library
Pincer ECE (E= N, P) transition-metal complexes, in which the terdentate ligands contain
two stable five-membered cyclometalated rings, have reached a high level of sophistication …

Metals and hydrogen bonds

L Brammer - Dalton Transactions, 2003 - pubs.rsc.org
The hydrogen bond is commonly considered to lie within the domain of organic or biological
chemistry, involving interactions of a hydrogen atom with two electronegative p-block …

A model for the interaction of trifluoroethanol with peptides and proteins

R Rajan, P Balaram - … journal of peptide and protein research, 1996 - Wiley Online Library
The structural stabilizing property of 2, 2, 2‐trifluoroethanol (TFE) in peptides has been
widely demon strated. More recently, TFE has been shown to enhance secondary structure …