Metal‐organic framework‐based single‐atom electro‐/photocatalysts: Synthesis, energy applications, and opportunities

M Ahmad, J Chen, J Liu, Y Zhang, Z Song… - Carbon …, 2024 - Wiley Online Library
Single‐atom catalysts (SACs) have gained substantial attention because of their exceptional
catalytic properties. However, the high surface energy limits their synthesis, thus creating …

Recent progress on NHC-stabilized early transition metal (group 3–7) complexes: Synthesis and applications

C Romain, S Bellemin-Laponnaz, S Dagorne - Coordination Chemistry …, 2020 - Elsevier
The present paper comprehensively reviews group 3–7 metal NHC complexes reported
since 2014, with emphasis on their current applications and fundamental reactivity. Thanks …

Coordination ring-opening polymerization of cyclic esters: A critical overview of DFT modeling and visualization of the reaction mechanisms

I Nifant'ev, P Ivchenko - Molecules, 2019 - mdpi.com
Ring-opening polymerization (ROP) of cyclic esters (lactones, lactides, cyclic carbonates
and phosphates) is an effective tool to synthesize biocompatible and biodegradable …

Mechanism of the Polymerization of rac-Lactide by Fast Zinc Alkoxide Catalysts

DE Stasiw, AM Luke, T Rosen, AB League… - Inorganic …, 2017 - ACS Publications
The ring-opening transesterification polymerization (ROTEP) of rac-lactide (rac-LA) using
LXZn catalysts (LX= ligand having phenolate, amine, and pyridine donors with variable para …

Synthesis and reactivity of N-heterocyclic carbene stabilized lanthanide (II) bis (amido) complexes

Z Pan, D Gao, C Zhang, L Guo, J Li, C Cui - Organometallics, 2021 - ACS Publications
Lanthanide amides are some of the most important reagents and catalysts in lanthanide
organometallic chemistry because of their high stability. Nevertheless, the readily available …

DFT Visualization and Experimental Evidence of BHT-Mg-Catalyzed Copolymerization of Lactides, Lactones and Ethylene Phosphates

I Nifant'ev, A Shlyakhtin, M Kosarev, D Gavrilov… - Polymers, 2019 - mdpi.com
Catalytic ring-opening polymerization (ROP) of cyclic esters (lactides, lactones) and cyclic
ethylene phosphates is an effective way to process materials with regulated hydrophilicity …

Mechanisms and origins of stereoselectivity of NHC-catalyzed reaction of aldehyde and butadienoate

Y Li, Z Zhang, Z Li - Molecular Catalysis, 2020 - Elsevier
The first computational study on the mechanisms and stereoselectivities of the reaction
between benzaldehyde and butadienoate generating E-4-oxo-2-butenoate catalyzed by N …

Understanding Catalyst Structural Effects on the Ring-Opening Polymerization of Cyclic Esters

AM Luke - 2020 - search.proquest.com
Materials derived from biomass feedstocks are considered sustainable substitutes for some
of the petrochemically-derived products used in commercially relevant polymers. One option …