The direct synthesis of dimethyl carbonate out of carbon dioxide and methanol is catalyzed by D-metals supported on various matrices

DJ Faria, LM dos Santos, FL Bernard, IS Pinto… - Journal of Molecular …, 2023 - Elsevier
The chemical transformation of carbon dioxide (CO 2) into valuable chemicals is a
fascinating way to reduce CO 2 concentration in the atmosphere. Dimethyl carbonate (DMC) …

CeO2 nanorods with bifunctional oxygen vacancies for promoting low-pressure photothermocatalytic CO2 conversion with CH3OH to dimethyl carbonate

S Jin, X Guan, X Zhang, C Zhang, J Liu, Y Wang… - Journal of …, 2023 - Elsevier
The direct synthesis of dimethyl carbonate (DMC) from CO 2 and methanol is a kind of highly-
attractive route for CO 2 conversion to high value-added chemicals. However, a key core …

Improvement of surface properties of metal doped-CeO2 nanospindle catalysts for direct synthesis of dimethyl carbonate from CO2 and methanol

P Seeharaj, T Saenman, T Phiwhom… - Journal of …, 2023 - Elsevier
To utilize carbon dioxide (CO 2) which is the main greenhouse gas, this study developed
effective metal doped-CeO 2 nanospindle catalysts for conversion of CO 2 and methanol …

Ga and Ti co-doped CeO 2 nanorod catalysts with enhanced activity towards the synthesis of dimethyl carbonate from CO 2 and methanol

X Wei, Y Xue, T Wan, B Da, F Wang - New Journal of Chemistry, 2024 - pubs.rsc.org
Novel Ga and Ti co-doped CeO2 nanorod catalysts were synthesized using a one-pot
hydrothermal process and characterized by XRD, TEM, FT-IR, Raman, N2 adsorption …

[HTML][HTML] Direct synthesis of dimethyl carbonate from methanol and carbon dioxide over Co-Ce-Zr ternary metal solid solution

X Li, L Cao, D Jia, Y Sun - Fuel Processing Technology, 2024 - Elsevier
To investigate highly performance catalysts for the direct synthesis of dimethyl carbonate
(DMC) from carbon dioxide (CO 2) and methanol, a Co 0.02/Ce 0.7 Zr 0.3 O 2 ternary metal …

Heteroatom-assisted oxygen vacancies in cerium oxide catalysts for efficient synthesis of dimethyl carbonate from CO 2 and methanol

N Maity, SA Al-Jendan, S Barman, N Kulal… - Catalysis Science & …, 2024 - pubs.rsc.org
The direct synthesis of dimethyl carbonate (DMC) from CO2 and methanol is a green
synthetic route owing to the nontoxicity of starting materials and synthetic protocol. One of …

[HTML][HTML] Ordered versus Non-Ordered Mesoporous CeO2-Based Systems for the Direct Synthesis of Dimethyl Carbonate from CO2

N Rusta, F Secci, V Mameli, C Cannas - Nanomaterials, 2024 - mdpi.com
In this work, non-ordered and ordered CeO2-based catalysts are proposed for CO2
conversion to dimethyl carbonate (DMC). Particularly, non-ordered mesoporous CeO2 …

Porous ceria materials for efficient direct conversion of carbon dioxide and methanol to dimethyl carbonate

Z Yang, JT Zheng, X Lu, MM Lin, D Cai, Y Wang… - Materials …, 2024 - pubs.rsc.org
Ceria (CeO2) is widely considered as a superior catalytic material for the direct conversion
of carbon dioxide (CO2) and methanol into dimethyl carbonate (DMC). Developing porous …

Surface engineering of CexBi1− xO2− δ nanorods rich in oxygen vacancies for enhancing photo-thermal synthesis of dimethyl carbonate from CO2/CH3OH

X Guan, S Jin, L Liu, X Zhao, X Zhang, C Zhang, Z Li… - Fuel, 2024 - Elsevier
The utilization of oxygen vacancies to modulate the surface properties of catalysts is a
powerful way to enhance catalytic activity. In this work, the doping effect of Bi 3+ on the …

Efficient Visible‐Light‐Assisted Synthesis of Dimethyl Carbonate from CO2 and Methanol by Ce–Metal Organic Framework‐Derived CeO2 Nanoparticles

X Guan, X Zhang, C Zhang, R Li, J Liu, Y Wang… - Solar …, 2023 - Wiley Online Library
The conversion of carbon dioxide to dimethyl carbonate (DMC) is an attractive process, but
thermodynamic limitations of the reaction hinder its further development. Herein, a simple …